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(Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate

The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intra­molecular N—H⋯O inter­action results in the formation of a planar six-membered ring, which is oriented at dihedral a...

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Detalles Bibliográficos
Autores principales: Zhao, Yong-Feng, Xiong, Jin-Ping, Zuo, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969241/
https://www.ncbi.nlm.nih.gov/pubmed/21582779
http://dx.doi.org/10.1107/S1600536809020224
Descripción
Sumario:The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intra­molecular N—H⋯O inter­action results in the formation of a planar six-membered ring, which is oriented at dihedral angles of 13.50 (4) and 4.49 (4)° with respect to the benzene ring and naphthalene ring system, respectively. In the crystal structure, inter­molecular C—H⋯O and C—H⋯N inter­actions link the mol­ecules into a two-dimensional network. π–π contacts between the naphthalene systems [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure.