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(Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate
The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intramolecular N—H⋯O interaction results in the formation of a planar six-membered ring, which is oriented at dihedral a...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969241/ https://www.ncbi.nlm.nih.gov/pubmed/21582779 http://dx.doi.org/10.1107/S1600536809020224 |
Sumario: | The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intramolecular N—H⋯O interaction results in the formation of a planar six-membered ring, which is oriented at dihedral angles of 13.50 (4) and 4.49 (4)° with respect to the benzene ring and naphthalene ring system, respectively. In the crystal structure, intermolecular C—H⋯O and C—H⋯N interactions link the molecules into a two-dimensional network. π–π contacts between the naphthalene systems [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. |
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