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(Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate
The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intramolecular N—H⋯O interaction results in the formation of a planar six-membered ring, which is oriented at dihedral a...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969241/ https://www.ncbi.nlm.nih.gov/pubmed/21582779 http://dx.doi.org/10.1107/S1600536809020224 |
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author | Zhao, Yong-Feng Xiong, Jin-Ping Zuo, Yu |
author_facet | Zhao, Yong-Feng Xiong, Jin-Ping Zuo, Yu |
author_sort | Zhao, Yong-Feng |
collection | PubMed |
description | The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intramolecular N—H⋯O interaction results in the formation of a planar six-membered ring, which is oriented at dihedral angles of 13.50 (4) and 4.49 (4)° with respect to the benzene ring and naphthalene ring system, respectively. In the crystal structure, intermolecular C—H⋯O and C—H⋯N interactions link the molecules into a two-dimensional network. π–π contacts between the naphthalene systems [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. |
format | Text |
id | pubmed-2969241 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29692412010-12-30 (Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate Zhao, Yong-Feng Xiong, Jin-Ping Zuo, Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intramolecular N—H⋯O interaction results in the formation of a planar six-membered ring, which is oriented at dihedral angles of 13.50 (4) and 4.49 (4)° with respect to the benzene ring and naphthalene ring system, respectively. In the crystal structure, intermolecular C—H⋯O and C—H⋯N interactions link the molecules into a two-dimensional network. π–π contacts between the naphthalene systems [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969241/ /pubmed/21582779 http://dx.doi.org/10.1107/S1600536809020224 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhao, Yong-Feng Xiong, Jin-Ping Zuo, Yu (Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate |
title | (Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate |
title_full | (Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate |
title_fullStr | (Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate |
title_full_unstemmed | (Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate |
title_short | (Z)-1-[(3-Cyanophenyl)iminiomethyl]-2-naphtholate |
title_sort | (z)-1-[(3-cyanophenyl)iminiomethyl]-2-naphtholate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969241/ https://www.ncbi.nlm.nih.gov/pubmed/21582779 http://dx.doi.org/10.1107/S1600536809020224 |
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