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(Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate

The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intra­molecular N—H⋯O inter­action results in the formation of a planar six-membered ring, which is oriented at dihedral a...

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Detalles Bibliográficos
Autores principales: Zhao, Yong-Feng, Xiong, Jin-Ping, Zuo, Yu
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969241/
https://www.ncbi.nlm.nih.gov/pubmed/21582779
http://dx.doi.org/10.1107/S1600536809020224
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author Zhao, Yong-Feng
Xiong, Jin-Ping
Zuo, Yu
author_facet Zhao, Yong-Feng
Xiong, Jin-Ping
Zuo, Yu
author_sort Zhao, Yong-Feng
collection PubMed
description The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intra­molecular N—H⋯O inter­action results in the formation of a planar six-membered ring, which is oriented at dihedral angles of 13.50 (4) and 4.49 (4)° with respect to the benzene ring and naphthalene ring system, respectively. In the crystal structure, inter­molecular C—H⋯O and C—H⋯N inter­actions link the mol­ecules into a two-dimensional network. π–π contacts between the naphthalene systems [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure.
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spelling pubmed-29692412010-12-30 (Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate Zhao, Yong-Feng Xiong, Jin-Ping Zuo, Yu Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(18)H(12)N(2)O, crystallizes in a zwitterionic form. The dihedral angle between the planes of the benzene ring and naphthalene ring system is 13.95 (5)°. An intra­molecular N—H⋯O inter­action results in the formation of a planar six-membered ring, which is oriented at dihedral angles of 13.50 (4) and 4.49 (4)° with respect to the benzene ring and naphthalene ring system, respectively. In the crystal structure, inter­molecular C—H⋯O and C—H⋯N inter­actions link the mol­ecules into a two-dimensional network. π–π contacts between the naphthalene systems [centroid–centroid distance = 3.974 (1) Å] may further stabilize the structure. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969241/ /pubmed/21582779 http://dx.doi.org/10.1107/S1600536809020224 Text en © Zhao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhao, Yong-Feng
Xiong, Jin-Ping
Zuo, Yu
(Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate
title (Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate
title_full (Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate
title_fullStr (Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate
title_full_unstemmed (Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate
title_short (Z)-1-[(3-Cyano­phen­yl)iminiometh­yl]-2-naphtholate
title_sort (z)-1-[(3-cyano­phen­yl)iminiometh­yl]-2-naphtholate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969241/
https://www.ncbi.nlm.nih.gov/pubmed/21582779
http://dx.doi.org/10.1107/S1600536809020224
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