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Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate

The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy­carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo­hexenone ring has an envelope conformation. In the crysta...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Göçmentürk, Mustafa, Ergün, Yavuz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969242/
https://www.ncbi.nlm.nih.gov/pubmed/21582955
http://dx.doi.org/10.1107/S160053680902385X
Descripción
Sumario:The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy­carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo­hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers with R (2) (2)(10) ring motifs. π–π contacts between parallel pyrrole rings [centroid–centroid distance = 3.776 (2) Å] may further stabilize the structure. A weak C—H⋯π inter­action is also observed.