Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate

The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy­carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo­hexenone ring has an envelope conformation. In the crysta...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Göçmentürk, Mustafa, Ergün, Yavuz
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969242/
https://www.ncbi.nlm.nih.gov/pubmed/21582955
http://dx.doi.org/10.1107/S160053680902385X
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Göçmentürk, Mustafa
Ergün, Yavuz
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Göçmentürk, Mustafa
Ergün, Yavuz
author_sort Hökelek, Tuncer
collection PubMed
description The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy­carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo­hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers with R (2) (2)(10) ring motifs. π–π contacts between parallel pyrrole rings [centroid–centroid distance = 3.776 (2) Å] may further stabilize the structure. A weak C—H⋯π inter­action is also observed.
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spelling pubmed-29692422010-12-30 Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate Hökelek, Tuncer Dal, Hakan Tercan, Barış Göçmentürk, Mustafa Ergün, Yavuz Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy­carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo­hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N—H⋯O hydrogen bonds link the mol­ecules into centrosymmetric dimers with R (2) (2)(10) ring motifs. π–π contacts between parallel pyrrole rings [centroid–centroid distance = 3.776 (2) Å] may further stabilize the structure. A weak C—H⋯π inter­action is also observed. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969242/ /pubmed/21582955 http://dx.doi.org/10.1107/S160053680902385X Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Göçmentürk, Mustafa
Ergün, Yavuz
Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate
title Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate
title_full Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate
title_fullStr Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate
title_full_unstemmed Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate
title_short Ethyl 1-oxo-1,2,3,4-tetra­hydro-9H-carbazole-3-carboxyl­ate
title_sort ethyl 1-oxo-1,2,3,4-tetra­hydro-9h-carbazole-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969242/
https://www.ncbi.nlm.nih.gov/pubmed/21582955
http://dx.doi.org/10.1107/S160053680902385X
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AT gocmenturkmustafa ethyl1oxo1234tetrahydro9hcarbazole3carboxylate
AT ergunyavuz ethyl1oxo1234tetrahydro9hcarbazole3carboxylate

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