catena-Poly[[[tetra­aqua­cobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 2-[4-(2-carboxyl­ato­eth­yl)phen­oxy]acetate]

In the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(11)H(10)O(5))}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4′-bipyridine ligands and four O atoms from four water mol­ecules in a slightly distorted octa­hedral coordination geometry. The 4,...

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Detalles Bibliográficos
Autores principales: Wang, Xi-Fang, Liu, Chong-Bo, Huang, De-He, Xiong, Zhi-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969250/
https://www.ncbi.nlm.nih.gov/pubmed/21582697
http://dx.doi.org/10.1107/S1600536809021552
Descripción
Sumario:In the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(11)H(10)O(5))}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4′-bipyridine ligands and four O atoms from four water mol­ecules in a slightly distorted octa­hedral coordination geometry. The 4,4′-bipyridine ligands bridge Co(II) ions into a one-dimensional chain structure. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dianions are completely disordered about an inversion center.

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