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catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate]
In the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(11)H(10)O(5))}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4′-bipyridine ligands and four O atoms from four water molecules in a slightly distorted octahedral coordination geometry. The 4,...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969250/ https://www.ncbi.nlm.nih.gov/pubmed/21582697 http://dx.doi.org/10.1107/S1600536809021552 |
| _version_ | 1782190089946791936 |
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| author | Wang, Xi-Fang Liu, Chong-Bo Huang, De-He Xiong, Zhi-Qiang |
| author_facet | Wang, Xi-Fang Liu, Chong-Bo Huang, De-He Xiong, Zhi-Qiang |
| author_sort | Wang, Xi-Fang |
| collection | PubMed |
| description | In the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(11)H(10)O(5))}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4′-bipyridine ligands and four O atoms from four water molecules in a slightly distorted octahedral coordination geometry. The 4,4′-bipyridine ligands bridge Co(II) ions into a one-dimensional chain structure. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dianions are completely disordered about an inversion center. |
| format | Text |
| id | pubmed-2969250 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692502010-12-30 catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] Wang, Xi-Fang Liu, Chong-Bo Huang, De-He Xiong, Zhi-Qiang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(11)H(10)O(5))}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4′-bipyridine ligands and four O atoms from four water molecules in a slightly distorted octahedral coordination geometry. The 4,4′-bipyridine ligands bridge Co(II) ions into a one-dimensional chain structure. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link cations and anions into a three-dimensional network. The dianions are completely disordered about an inversion center. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969250/ /pubmed/21582697 http://dx.doi.org/10.1107/S1600536809021552 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Xi-Fang Liu, Chong-Bo Huang, De-He Xiong, Zhi-Qiang catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2) N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] |
| title |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] |
| title_full |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] |
| title_fullStr |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] |
| title_full_unstemmed |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] |
| title_short |
catena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ(2)
N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] |
| title_sort | catena-poly[[[tetraaquacobalt(ii)]-μ-4,4′-bipyridine-κ(2)
n:n′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969250/ https://www.ncbi.nlm.nih.gov/pubmed/21582697 http://dx.doi.org/10.1107/S1600536809021552 |
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