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{Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3) P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate
In the title compound, [PtCl(C(34)H(33)P(3))]PF(6), the Pt(II) cation adopts a distorted square-planar PtClP(3) geometry, arising from the P,P′,P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF(6) (−) anion are disordered over two sets of positions in a 0.614 (17):0.386...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969258/ https://www.ncbi.nlm.nih.gov/pubmed/21582720 http://dx.doi.org/10.1107/S1600536809022405 |
| _version_ | 1782190093089374208 |
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| author | Heston, Scott A. Noll, Bruce C. Helm, Monte L. |
| author_facet | Heston, Scott A. Noll, Bruce C. Helm, Monte L. |
| author_sort | Heston, Scott A. |
| collection | PubMed |
| description | In the title compound, [PtCl(C(34)H(33)P(3))]PF(6), the Pt(II) cation adopts a distorted square-planar PtClP(3) geometry, arising from the P,P′,P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF(6) (−) anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio. |
| format | Text |
| id | pubmed-2969258 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692582010-12-30 {Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3) P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate Heston, Scott A. Noll, Bruce C. Helm, Monte L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [PtCl(C(34)H(33)P(3))]PF(6), the Pt(II) cation adopts a distorted square-planar PtClP(3) geometry, arising from the P,P′,P′′-tridentate triphos ligand and a chloride ion. Four of the F atoms of the PF(6) (−) anion are disordered over two sets of positions in a 0.614 (17):0.386 (17) ratio. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969258/ /pubmed/21582720 http://dx.doi.org/10.1107/S1600536809022405 Text en © Heston et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Heston, Scott A. Noll, Bruce C. Helm, Monte L. {Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3) P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate |
| title | {Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3)
P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate |
| title_full | {Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3)
P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate |
| title_fullStr | {Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3)
P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate |
| title_full_unstemmed | {Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3)
P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate |
| title_short | {Bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3)
P,P′,P′′}chloridoplatinium(II) hexafluoridophosphate |
| title_sort | {bis[2-(diphenylphosphino)ethyl]phenylphosphine-κ(3)
p,p′,p′′}chloridoplatinium(ii) hexafluoridophosphate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969258/ https://www.ncbi.nlm.nih.gov/pubmed/21582720 http://dx.doi.org/10.1107/S1600536809022405 |
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