Cargando…

Bis(triethano­lamine)nickel(II) sulfate

The title compound, [Ni(C(6)H(15)NO(3))(2)]SO(4), contains two triethano­lamine (TEA) ligands bound to an Ni(2+) metal centre, which lies on a crystallographic inversion centre, and one sulfate anion located on a twofold rotation axis such that the asymmetric unit contains one-half molecule of the c...

Descripción completa

Detalles Bibliográficos
Autores principales: Guo, Hong-Xu, Du, Zi-Xian, Li, Xi-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969259/
https://www.ncbi.nlm.nih.gov/pubmed/21582734
http://dx.doi.org/10.1107/S1600536809023046
_version_ 1782190093320060928
author Guo, Hong-Xu
Du, Zi-Xian
Li, Xi-Zhong
author_facet Guo, Hong-Xu
Du, Zi-Xian
Li, Xi-Zhong
author_sort Guo, Hong-Xu
collection PubMed
description The title compound, [Ni(C(6)H(15)NO(3))(2)]SO(4), contains two triethano­lamine (TEA) ligands bound to an Ni(2+) metal centre, which lies on a crystallographic inversion centre, and one sulfate anion located on a twofold rotation axis such that the asymmetric unit contains one-half molecule of the cation and of the anion. The triethano­lamine ligands coordinate via each axial N atom and two of the three O atoms, while the third arm of the ligand has the hydroxyl group pointing away from the metal centre. The sulfate anions are hydrogen bonded to the coordinated hydroxyl groups and also to the free arm, forming a two-dimensional supra­molecular hydrogen-bonded network expanding parallel to (010).
format Text
id pubmed-2969259
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29692592010-12-30 Bis(triethano­lamine)nickel(II) sulfate Guo, Hong-Xu Du, Zi-Xian Li, Xi-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(6)H(15)NO(3))(2)]SO(4), contains two triethano­lamine (TEA) ligands bound to an Ni(2+) metal centre, which lies on a crystallographic inversion centre, and one sulfate anion located on a twofold rotation axis such that the asymmetric unit contains one-half molecule of the cation and of the anion. The triethano­lamine ligands coordinate via each axial N atom and two of the three O atoms, while the third arm of the ligand has the hydroxyl group pointing away from the metal centre. The sulfate anions are hydrogen bonded to the coordinated hydroxyl groups and also to the free arm, forming a two-dimensional supra­molecular hydrogen-bonded network expanding parallel to (010). International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969259/ /pubmed/21582734 http://dx.doi.org/10.1107/S1600536809023046 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guo, Hong-Xu
Du, Zi-Xian
Li, Xi-Zhong
Bis(triethano­lamine)nickel(II) sulfate
title Bis(triethano­lamine)nickel(II) sulfate
title_full Bis(triethano­lamine)nickel(II) sulfate
title_fullStr Bis(triethano­lamine)nickel(II) sulfate
title_full_unstemmed Bis(triethano­lamine)nickel(II) sulfate
title_short Bis(triethano­lamine)nickel(II) sulfate
title_sort bis(triethano­lamine)nickel(ii) sulfate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969259/
https://www.ncbi.nlm.nih.gov/pubmed/21582734
http://dx.doi.org/10.1107/S1600536809023046
work_keys_str_mv AT guohongxu bistriethanolaminenickeliisulfate
AT duzixian bistriethanolaminenickeliisulfate
AT lixizhong bistriethanolaminenickeliisulfate