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Bis(triethanolamine)nickel(II) sulfate
The title compound, [Ni(C(6)H(15)NO(3))(2)]SO(4), contains two triethanolamine (TEA) ligands bound to an Ni(2+) metal centre, which lies on a crystallographic inversion centre, and one sulfate anion located on a twofold rotation axis such that the asymmetric unit contains one-half molecule of the c...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969259/ https://www.ncbi.nlm.nih.gov/pubmed/21582734 http://dx.doi.org/10.1107/S1600536809023046 |
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author | Guo, Hong-Xu Du, Zi-Xian Li, Xi-Zhong |
author_facet | Guo, Hong-Xu Du, Zi-Xian Li, Xi-Zhong |
author_sort | Guo, Hong-Xu |
collection | PubMed |
description | The title compound, [Ni(C(6)H(15)NO(3))(2)]SO(4), contains two triethanolamine (TEA) ligands bound to an Ni(2+) metal centre, which lies on a crystallographic inversion centre, and one sulfate anion located on a twofold rotation axis such that the asymmetric unit contains one-half molecule of the cation and of the anion. The triethanolamine ligands coordinate via each axial N atom and two of the three O atoms, while the third arm of the ligand has the hydroxyl group pointing away from the metal centre. The sulfate anions are hydrogen bonded to the coordinated hydroxyl groups and also to the free arm, forming a two-dimensional supramolecular hydrogen-bonded network expanding parallel to (010). |
format | Text |
id | pubmed-2969259 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29692592010-12-30 Bis(triethanolamine)nickel(II) sulfate Guo, Hong-Xu Du, Zi-Xian Li, Xi-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Ni(C(6)H(15)NO(3))(2)]SO(4), contains two triethanolamine (TEA) ligands bound to an Ni(2+) metal centre, which lies on a crystallographic inversion centre, and one sulfate anion located on a twofold rotation axis such that the asymmetric unit contains one-half molecule of the cation and of the anion. The triethanolamine ligands coordinate via each axial N atom and two of the three O atoms, while the third arm of the ligand has the hydroxyl group pointing away from the metal centre. The sulfate anions are hydrogen bonded to the coordinated hydroxyl groups and also to the free arm, forming a two-dimensional supramolecular hydrogen-bonded network expanding parallel to (010). International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969259/ /pubmed/21582734 http://dx.doi.org/10.1107/S1600536809023046 Text en © Guo et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Guo, Hong-Xu Du, Zi-Xian Li, Xi-Zhong Bis(triethanolamine)nickel(II) sulfate |
title | Bis(triethanolamine)nickel(II) sulfate |
title_full | Bis(triethanolamine)nickel(II) sulfate |
title_fullStr | Bis(triethanolamine)nickel(II) sulfate |
title_full_unstemmed | Bis(triethanolamine)nickel(II) sulfate |
title_short | Bis(triethanolamine)nickel(II) sulfate |
title_sort | bis(triethanolamine)nickel(ii) sulfate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969259/ https://www.ncbi.nlm.nih.gov/pubmed/21582734 http://dx.doi.org/10.1107/S1600536809023046 |
work_keys_str_mv | AT guohongxu bistriethanolaminenickeliisulfate AT duzixian bistriethanolaminenickeliisulfate AT lixizhong bistriethanolaminenickeliisulfate |