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2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol
The molecule of the title compound, C(27)H(26)N(2)O(4), lies across a crystallographic inversion centre and adopts an l-shaped configuration. Within the molecule, the two naphthalene units are approximately perpendicular, making a dihedral angle of 80.24 (5)°. The two intramolecular O—H⋯N hydrogen...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969260/ https://www.ncbi.nlm.nih.gov/pubmed/21582919 http://dx.doi.org/10.1107/S1600536809023241 |
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author | Dong, Wen-Kui Wu, Jian-Chao Sun, Yin-Xia Li, Li Yao, Jian |
author_facet | Dong, Wen-Kui Wu, Jian-Chao Sun, Yin-Xia Li, Li Yao, Jian |
author_sort | Dong, Wen-Kui |
collection | PubMed |
description | The molecule of the title compound, C(27)H(26)N(2)O(4), lies across a crystallographic inversion centre and adopts an l-shaped configuration. Within the molecule, the two naphthalene units are approximately perpendicular, making a dihedral angle of 80.24 (5)°. The two intramolecular O—H⋯N hydrogen bonds, generate S(6) ring motifs. In the crystal structure, every molecule links five other molecules into an infinite cross-linked layered supramolecular structure via intermolecular C—H⋯O hydrogen bonds, C—H⋯π interactions and π–π stacking interactions [centroid–centroid distance = 3.956 (4) Å]. |
format | Text |
id | pubmed-2969260 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29692602010-12-30 2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol Dong, Wen-Kui Wu, Jian-Chao Sun, Yin-Xia Li, Li Yao, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The molecule of the title compound, C(27)H(26)N(2)O(4), lies across a crystallographic inversion centre and adopts an l-shaped configuration. Within the molecule, the two naphthalene units are approximately perpendicular, making a dihedral angle of 80.24 (5)°. The two intramolecular O—H⋯N hydrogen bonds, generate S(6) ring motifs. In the crystal structure, every molecule links five other molecules into an infinite cross-linked layered supramolecular structure via intermolecular C—H⋯O hydrogen bonds, C—H⋯π interactions and π–π stacking interactions [centroid–centroid distance = 3.956 (4) Å]. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969260/ /pubmed/21582919 http://dx.doi.org/10.1107/S1600536809023241 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Dong, Wen-Kui Wu, Jian-Chao Sun, Yin-Xia Li, Li Yao, Jian 2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol |
title | 2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol |
title_full | 2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol |
title_fullStr | 2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol |
title_full_unstemmed | 2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol |
title_short | 2,2′-[1,1′-(Propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol |
title_sort | 2,2′-[1,1′-(propane-1,3-diyldioxydinitrilo)diethylidyne]di-1-naphthol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969260/ https://www.ncbi.nlm.nih.gov/pubmed/21582919 http://dx.doi.org/10.1107/S1600536809023241 |
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