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2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol

The mol­ecule of the title compound, C(27)H(26)N(2)O(4), lies across a crystallographic inversion centre and adopts an l-shaped configuration. Within the mol­ecule, the two naphthalene units are approximately perpendicular, making a dihedral angle of 80.24 (5)°. The two intramolecular O—H⋯N hydrogen...

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Detalles Bibliográficos
Autores principales: Dong, Wen-Kui, Wu, Jian-Chao, Sun, Yin-Xia, Li, Li, Yao, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969260/
https://www.ncbi.nlm.nih.gov/pubmed/21582919
http://dx.doi.org/10.1107/S1600536809023241
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author Dong, Wen-Kui
Wu, Jian-Chao
Sun, Yin-Xia
Li, Li
Yao, Jian
author_facet Dong, Wen-Kui
Wu, Jian-Chao
Sun, Yin-Xia
Li, Li
Yao, Jian
author_sort Dong, Wen-Kui
collection PubMed
description The mol­ecule of the title compound, C(27)H(26)N(2)O(4), lies across a crystallographic inversion centre and adopts an l-shaped configuration. Within the mol­ecule, the two naphthalene units are approximately perpendicular, making a dihedral angle of 80.24 (5)°. The two intramolecular O—H⋯N hydrogen bonds, generate S(6) ring motifs. In the crystal structure, every mol­ecule links five other mol­ecules into an infinite cross-linked layered supra­molecular structure via inter­molecular C—H⋯O hydrogen bonds, C—H⋯π inter­actions and π–π stacking inter­actions [centroid–centroid distance = 3.956 (4) Å].
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spelling pubmed-29692602010-12-30 2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol Dong, Wen-Kui Wu, Jian-Chao Sun, Yin-Xia Li, Li Yao, Jian Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(27)H(26)N(2)O(4), lies across a crystallographic inversion centre and adopts an l-shaped configuration. Within the mol­ecule, the two naphthalene units are approximately perpendicular, making a dihedral angle of 80.24 (5)°. The two intramolecular O—H⋯N hydrogen bonds, generate S(6) ring motifs. In the crystal structure, every mol­ecule links five other mol­ecules into an infinite cross-linked layered supra­molecular structure via inter­molecular C—H⋯O hydrogen bonds, C—H⋯π inter­actions and π–π stacking inter­actions [centroid–centroid distance = 3.956 (4) Å]. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969260/ /pubmed/21582919 http://dx.doi.org/10.1107/S1600536809023241 Text en © Dong et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Dong, Wen-Kui
Wu, Jian-Chao
Sun, Yin-Xia
Li, Li
Yao, Jian
2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol
title 2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol
title_full 2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol
title_fullStr 2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol
title_full_unstemmed 2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol
title_short 2,2′-[1,1′-(Propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol
title_sort 2,2′-[1,1′-(propane-1,3-diyldioxy­dinitrilo)diethyl­idyne]di-1-naphthol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969260/
https://www.ncbi.nlm.nih.gov/pubmed/21582919
http://dx.doi.org/10.1107/S1600536809023241
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