Cargando…
{2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4) O (1),N,N′,O (1′)}cobalt(II) monohydrate
In the title complex, [Co(C(22)H(24)N(2)O(4))]·H(2)O, the Co(II) atom is in an almost square-planar coordination environment involving two O and two N atoms from the Schiff base ligand. A water molecule cocrystallizes with the coordination compound and may be held in the crystal by O—H⋯O hydrogen...
| Autores principales: | , , , , |
|---|---|
| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969264/ https://www.ncbi.nlm.nih.gov/pubmed/21582700 http://dx.doi.org/10.1107/S1600536809021540 |
| _version_ | 1782190094898167808 |
|---|---|
| author | Bao, Yan Li, Hong-Feng Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng |
| author_facet | Bao, Yan Li, Hong-Feng Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng |
| author_sort | Bao, Yan |
| collection | PubMed |
| description | In the title complex, [Co(C(22)H(24)N(2)O(4))]·H(2)O, the Co(II) atom is in an almost square-planar coordination environment involving two O and two N atoms from the Schiff base ligand. A water molecule cocrystallizes with the coordination compound and may be held in the crystal by O—H⋯O hydrogen bonds. Heteroatomic π–π ring interactions may be present between symmetry-related complexes, with centroid–centroid distances of 3.5661 (8) Å. |
| format | Text |
| id | pubmed-2969264 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692642010-12-30 {2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4) O (1),N,N′,O (1′)}cobalt(II) monohydrate Bao, Yan Li, Hong-Feng Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Co(C(22)H(24)N(2)O(4))]·H(2)O, the Co(II) atom is in an almost square-planar coordination environment involving two O and two N atoms from the Schiff base ligand. A water molecule cocrystallizes with the coordination compound and may be held in the crystal by O—H⋯O hydrogen bonds. Heteroatomic π–π ring interactions may be present between symmetry-related complexes, with centroid–centroid distances of 3.5661 (8) Å. International Union of Crystallography 2009-06-13 /pmc/articles/PMC2969264/ /pubmed/21582700 http://dx.doi.org/10.1107/S1600536809021540 Text en © Bao et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Bao, Yan Li, Hong-Feng Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng {2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4) O (1),N,N′,O (1′)}cobalt(II) monohydrate |
| title | {2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(II) monohydrate |
| title_full | {2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(II) monohydrate |
| title_fullStr | {2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(II) monohydrate |
| title_full_unstemmed | {2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(II) monohydrate |
| title_short | {2,2′-[6,6′-Dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
O
(1),N,N′,O
(1′)}cobalt(II) monohydrate |
| title_sort | {2,2′-[6,6′-dimethoxycyclohexane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(4)
o
(1),n,n′,o
(1′)}cobalt(ii) monohydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969264/ https://www.ncbi.nlm.nih.gov/pubmed/21582700 http://dx.doi.org/10.1107/S1600536809021540 |
| work_keys_str_mv | AT baoyan 2266dimethoxycyclohexane12diylbisnitrilomethylidynediphenolatok4o1nno1cobaltiimonohydrate AT lihongfeng 2266dimethoxycyclohexane12diylbisnitrilomethylidynediphenolatok4o1nno1cobaltiimonohydrate AT yanpengfei 2266dimethoxycyclohexane12diylbisnitrilomethylidynediphenolatok4o1nno1cobaltiimonohydrate AT liguangming 2266dimethoxycyclohexane12diylbisnitrilomethylidynediphenolatok4o1nno1cobaltiimonohydrate AT houguangfeng 2266dimethoxycyclohexane12diylbisnitrilomethylidynediphenolatok4o1nno1cobaltiimonohydrate |