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Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate

In the crystal structure of the title compound {systematic name: diaquabis­[1-cyclo­propyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro­quinoline-3-carboxyl­ato]manganese(II) 2,2′-bi­pyridine solvate tetrahydrate}, [Mn(C(17)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O and one...

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Autores principales: Wang, Yan-Jun, Wang, Na, Hu, Rui-Ding, Lin, Qiu-Yue, Wang, Yun-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969266/
https://www.ncbi.nlm.nih.gov/pubmed/21582711
http://dx.doi.org/10.1107/S1600536809021783
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author Wang, Yan-Jun
Wang, Na
Hu, Rui-Ding
Lin, Qiu-Yue
Wang, Yun-Yun
author_facet Wang, Yan-Jun
Wang, Na
Hu, Rui-Ding
Lin, Qiu-Yue
Wang, Yun-Yun
author_sort Wang, Yan-Jun
collection PubMed
description In the crystal structure of the title compound {systematic name: diaquabis­[1-cyclo­propyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro­quinoline-3-carboxyl­ato]manganese(II) 2,2′-bi­pyridine solvate tetrahydrate}, [Mn(C(17)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O and one carboxyl­ate O atom of the two ciprofloxacin ligands are bound to the Mn(II) ion and occupy the equatorial positions, while the two aqua O atoms lie in the apical positions resulting in a distorted octa­hedral geometry. The crystal packing is stabilized by N–H⋯O and O–H⋯O hydrogen bonding interactions.
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spelling pubmed-29692662010-12-30 Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate Wang, Yan-Jun Wang, Na Hu, Rui-Ding Lin, Qiu-Yue Wang, Yun-Yun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title compound {systematic name: diaquabis­[1-cyclo­propyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro­quinoline-3-carboxyl­ato]manganese(II) 2,2′-bi­pyridine solvate tetrahydrate}, [Mn(C(17)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O and one carboxyl­ate O atom of the two ciprofloxacin ligands are bound to the Mn(II) ion and occupy the equatorial positions, while the two aqua O atoms lie in the apical positions resulting in a distorted octa­hedral geometry. The crystal packing is stabilized by N–H⋯O and O–H⋯O hydrogen bonding interactions. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969266/ /pubmed/21582711 http://dx.doi.org/10.1107/S1600536809021783 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Yan-Jun
Wang, Na
Hu, Rui-Ding
Lin, Qiu-Yue
Wang, Yun-Yun
Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate
title Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate
title_full Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate
title_fullStr Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate
title_full_unstemmed Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate
title_short Diaqua­bis(ciprofloxacinato)manganese(II) 2,2′-bipyridine solvate tetrahydrate
title_sort diaqua­bis(ciprofloxacinato)manganese(ii) 2,2′-bipyridine solvate tetrahydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969266/
https://www.ncbi.nlm.nih.gov/pubmed/21582711
http://dx.doi.org/10.1107/S1600536809021783
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