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(Methyldiphenylphosphoranylidene)ammonium chloride
The title compound, C(13)H(15)NP(+)·Cl(−), was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyliminophosphine. The dihedral angle between the phenyl rings in the cation is 61.5 (3)°. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds links the two components,...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969268/ https://www.ncbi.nlm.nih.gov/pubmed/21582794 http://dx.doi.org/10.1107/S1600536809020698 |
| _version_ | 1782190096037969920 |
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| author | Valerio-Cárdenas, Cintya Ortiz-Frade, Luis Grévy M., Jean-Michel |
| author_facet | Valerio-Cárdenas, Cintya Ortiz-Frade, Luis Grévy M., Jean-Michel |
| author_sort | Valerio-Cárdenas, Cintya |
| collection | PubMed |
| description | The title compound, C(13)H(15)NP(+)·Cl(−), was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyliminophosphine. The dihedral angle between the phenyl rings in the cation is 61.5 (3)°. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds links the two components, forming a centrosymmetric 2 + 2 aggregate. |
| format | Text |
| id | pubmed-2969268 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692682010-12-30 (Methyldiphenylphosphoranylidene)ammonium chloride Valerio-Cárdenas, Cintya Ortiz-Frade, Luis Grévy M., Jean-Michel Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(13)H(15)NP(+)·Cl(−), was obtained by hydrolysis of the N-trimethysilyl derivative of methydiphenyliminophosphine. The dihedral angle between the phenyl rings in the cation is 61.5 (3)°. In the crystal structure, intermolecular N—H⋯Cl hydrogen bonds links the two components, forming a centrosymmetric 2 + 2 aggregate. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969268/ /pubmed/21582794 http://dx.doi.org/10.1107/S1600536809020698 Text en © Valerio-Cárdenas et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Valerio-Cárdenas, Cintya Ortiz-Frade, Luis Grévy M., Jean-Michel (Methyldiphenylphosphoranylidene)ammonium chloride |
| title | (Methyldiphenylphosphoranylidene)ammonium chloride |
| title_full | (Methyldiphenylphosphoranylidene)ammonium chloride |
| title_fullStr | (Methyldiphenylphosphoranylidene)ammonium chloride |
| title_full_unstemmed | (Methyldiphenylphosphoranylidene)ammonium chloride |
| title_short | (Methyldiphenylphosphoranylidene)ammonium chloride |
| title_sort | (methyldiphenylphosphoranylidene)ammonium chloride |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969268/ https://www.ncbi.nlm.nih.gov/pubmed/21582794 http://dx.doi.org/10.1107/S1600536809020698 |
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