4-Methyl-3-nitro­pyridin-2-amine

In the title compound, C(6)H(7)N(3)O(2), the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H⋯N hydrogen bonds occur, resulting in R (2) (2)(8) rings. The packing is stabili...

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Autores principales: Khan, Misbahul Ain, Tahir, M. Nawaz, Ather, Abdul Qayyum, Shaheen, Maryam, Khan, Rauf Ahmad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969271/
https://www.ncbi.nlm.nih.gov/pubmed/21582886
http://dx.doi.org/10.1107/S1600536809022582
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author Khan, Misbahul Ain
Tahir, M. Nawaz
Ather, Abdul Qayyum
Shaheen, Maryam
Khan, Rauf Ahmad
author_facet Khan, Misbahul Ain
Tahir, M. Nawaz
Ather, Abdul Qayyum
Shaheen, Maryam
Khan, Rauf Ahmad
author_sort Khan, Misbahul Ain
collection PubMed
description In the title compound, C(6)H(7)N(3)O(2), the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H⋯N hydrogen bonds occur, resulting in R (2) (2)(8) rings. The packing is stabilized by aromatic π–π stacking [centroid–centroid distance = 3.5666 (15) Å] and a short N—O⋯π contact is seen.
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spelling pubmed-29692712010-12-30 4-Methyl-3-nitro­pyridin-2-amine Khan, Misbahul Ain Tahir, M. Nawaz Ather, Abdul Qayyum Shaheen, Maryam Khan, Rauf Ahmad Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(6)H(7)N(3)O(2), the dihedral angle between the nitro group and the pyridine ring is 15.5 (3)° and an intra­molecular N—H⋯O hydrogen bond occurs. In the crystal, inversion dimers linked by two N—H⋯N hydrogen bonds occur, resulting in R (2) (2)(8) rings. The packing is stabilized by aromatic π–π stacking [centroid–centroid distance = 3.5666 (15) Å] and a short N—O⋯π contact is seen. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969271/ /pubmed/21582886 http://dx.doi.org/10.1107/S1600536809022582 Text en © Khan et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khan, Misbahul Ain
Tahir, M. Nawaz
Ather, Abdul Qayyum
Shaheen, Maryam
Khan, Rauf Ahmad
4-Methyl-3-nitro­pyridin-2-amine
title 4-Methyl-3-nitro­pyridin-2-amine
title_full 4-Methyl-3-nitro­pyridin-2-amine
title_fullStr 4-Methyl-3-nitro­pyridin-2-amine
title_full_unstemmed 4-Methyl-3-nitro­pyridin-2-amine
title_short 4-Methyl-3-nitro­pyridin-2-amine
title_sort 4-methyl-3-nitro­pyridin-2-amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969271/
https://www.ncbi.nlm.nih.gov/pubmed/21582886
http://dx.doi.org/10.1107/S1600536809022582
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AT tahirmnawaz 4methyl3nitropyridin2amine
AT atherabdulqayyum 4methyl3nitropyridin2amine
AT shaheenmaryam 4methyl3nitropyridin2amine
AT khanraufahmad 4methyl3nitropyridin2amine

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