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Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)
The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydrothermal reaction of ZnBr(2) with 2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octahedral environment with two planar trans-related N,N′-chelating 2-[5-(2-...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969273/ https://www.ncbi.nlm.nih.gov/pubmed/21582749 http://dx.doi.org/10.1107/S1600536809023940 |
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author | Wang, Bo |
author_facet | Wang, Bo |
author_sort | Wang, Bo |
collection | PubMed |
description | The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydrothermal reaction of ZnBr(2) with 2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octahedral environment with two planar trans-related N,N′-chelating 2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetic acid ligands in the equatorial plane and two water molecules in the axial positions. In the crystal, O—H⋯O hydrogen bonds generate an infinite three-dimensional network. |
format | Text |
id | pubmed-2969273 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29692732010-12-30 Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II) Wang, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydrothermal reaction of ZnBr(2) with 2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octahedral environment with two planar trans-related N,N′-chelating 2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetic acid ligands in the equatorial plane and two water molecules in the axial positions. In the crystal, O—H⋯O hydrogen bonds generate an infinite three-dimensional network. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969273/ /pubmed/21582749 http://dx.doi.org/10.1107/S1600536809023940 Text en © Bo Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Bo Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II) |
title | Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2)
N
(4),N
(5)}zinc(II) |
title_full | Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2)
N
(4),N
(5)}zinc(II) |
title_fullStr | Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2)
N
(4),N
(5)}zinc(II) |
title_full_unstemmed | Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2)
N
(4),N
(5)}zinc(II) |
title_short | Diaquabis{2-[5-(2-pyridyl)-2H-tetrazol-2-yl]acetato-κ(2)
N
(4),N
(5)}zinc(II) |
title_sort | diaquabis{2-[5-(2-pyridyl)-2h-tetrazol-2-yl]acetato-κ(2)
n
(4),n
(5)}zinc(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969273/ https://www.ncbi.nlm.nih.gov/pubmed/21582749 http://dx.doi.org/10.1107/S1600536809023940 |
work_keys_str_mv | AT wangbo diaquabis252pyridyl2htetrazol2ylacetatok2n4n5zincii |