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Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)

The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydro­thermal reaction of ZnBr(2) with 2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octa­hedral environment with two planar trans-related N,N′-chelating 2-[5-(2-...

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Detalles Bibliográficos
Autor principal: Wang, Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969273/
https://www.ncbi.nlm.nih.gov/pubmed/21582749
http://dx.doi.org/10.1107/S1600536809023940
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author Wang, Bo
author_facet Wang, Bo
author_sort Wang, Bo
collection PubMed
description The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydro­thermal reaction of ZnBr(2) with 2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octa­hedral environment with two planar trans-related N,N′-chelating 2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetic acid ligands in the equatorial plane and two water mol­ecules in the axial positions. In the crystal, O—H⋯O hydrogen bonds generate an infinite three-dimensional network.
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spelling pubmed-29692732010-12-30 Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II) Wang, Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(8)H(6)N(5)O(2))(2)(H(2)O)(2)], was synthesized by hydro­thermal reaction of ZnBr(2) with 2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetic acid. The Zn(II) atom lies on an inversion center in a distorted octa­hedral environment with two planar trans-related N,N′-chelating 2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetic acid ligands in the equatorial plane and two water mol­ecules in the axial positions. In the crystal, O—H⋯O hydrogen bonds generate an infinite three-dimensional network. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969273/ /pubmed/21582749 http://dx.doi.org/10.1107/S1600536809023940 Text en © Bo Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Bo
Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)
title Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)
title_full Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)
title_fullStr Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)
title_full_unstemmed Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)
title_short Diaqua­bis{2-[5-(2-pyrid­yl)-2H-tetra­zol-2-yl]acetato-κ(2) N (4),N (5)}zinc(II)
title_sort diaqua­bis{2-[5-(2-pyrid­yl)-2h-tetra­zol-2-yl]acetato-κ(2) n (4),n (5)}zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969273/
https://www.ncbi.nlm.nih.gov/pubmed/21582749
http://dx.doi.org/10.1107/S1600536809023940
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