Cargando…

3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline

In the title compound, C(20)H(14)FN(3)O, the quinoxaline system makes dihedral angles of 32.38 (7) and 48.04 (7)° with the 4-fluoro­phenyl and pyridine rings, respectively. The 4-fluoro­phenyl ring makes a dihedral angle of 57.77 (9)° with the pyridine ring. In the crystal, the mol­ecules form dimer...

Descripción completa

Detalles Bibliográficos
Autores principales: Jahns, Hartmut, Koch, Pierre, Schollmeyer, Dieter, Laufer, Stefan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969274/
https://www.ncbi.nlm.nih.gov/pubmed/21582893
http://dx.doi.org/10.1107/S1600536809022119
_version_ 1782190097685282816
author Jahns, Hartmut
Koch, Pierre
Schollmeyer, Dieter
Laufer, Stefan
author_facet Jahns, Hartmut
Koch, Pierre
Schollmeyer, Dieter
Laufer, Stefan
author_sort Jahns, Hartmut
collection PubMed
description In the title compound, C(20)H(14)FN(3)O, the quinoxaline system makes dihedral angles of 32.38 (7) and 48.04 (7)° with the 4-fluoro­phenyl and pyridine rings, respectively. The 4-fluoro­phenyl ring makes a dihedral angle of 57.77 (9)° with the pyridine ring. In the crystal, the mol­ecules form dimeric C—H⋯N hydrogen-bonded R (2) (2)(20) ring motifs lying about crystallographic inversion centers. The dimeric units stack via π–π inter­actions between methoxy­phenyl rings and pyridine–fluoro­phenyl rings with centroid–centroid distances of 3.720 (1) and 3.823 (1) Å, respectively. The respective average perpendicular distances are 3.421 and 3.378 Å, with dihedral angles between the rings of 1.31 (9) and 11.64 (9)°.
format Text
id pubmed-2969274
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29692742010-12-30 3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline Jahns, Hartmut Koch, Pierre Schollmeyer, Dieter Laufer, Stefan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(14)FN(3)O, the quinoxaline system makes dihedral angles of 32.38 (7) and 48.04 (7)° with the 4-fluoro­phenyl and pyridine rings, respectively. The 4-fluoro­phenyl ring makes a dihedral angle of 57.77 (9)° with the pyridine ring. In the crystal, the mol­ecules form dimeric C—H⋯N hydrogen-bonded R (2) (2)(20) ring motifs lying about crystallographic inversion centers. The dimeric units stack via π–π inter­actions between methoxy­phenyl rings and pyridine–fluoro­phenyl rings with centroid–centroid distances of 3.720 (1) and 3.823 (1) Å, respectively. The respective average perpendicular distances are 3.421 and 3.378 Å, with dihedral angles between the rings of 1.31 (9) and 11.64 (9)°. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969274/ /pubmed/21582893 http://dx.doi.org/10.1107/S1600536809022119 Text en © Jahns et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jahns, Hartmut
Koch, Pierre
Schollmeyer, Dieter
Laufer, Stefan
3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline
title 3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline
title_full 3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline
title_fullStr 3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline
title_full_unstemmed 3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline
title_short 3-(4-Fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline
title_sort 3-(4-fluoro­phen­yl)-6-meth­oxy-2-(4-pyrid­yl)quinoxaline
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969274/
https://www.ncbi.nlm.nih.gov/pubmed/21582893
http://dx.doi.org/10.1107/S1600536809022119
work_keys_str_mv AT jahnshartmut 34fluorophenyl6methoxy24pyridylquinoxaline
AT kochpierre 34fluorophenyl6methoxy24pyridylquinoxaline
AT schollmeyerdieter 34fluorophenyl6methoxy24pyridylquinoxaline
AT lauferstefan 34fluorophenyl6methoxy24pyridylquinoxaline