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3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline
In the title compound, C(20)H(14)FN(3)O, the quinoxaline system makes dihedral angles of 32.38 (7) and 48.04 (7)° with the 4-fluorophenyl and pyridine rings, respectively. The 4-fluorophenyl ring makes a dihedral angle of 57.77 (9)° with the pyridine ring. In the crystal, the molecules form dimer...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969274/ https://www.ncbi.nlm.nih.gov/pubmed/21582893 http://dx.doi.org/10.1107/S1600536809022119 |
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author | Jahns, Hartmut Koch, Pierre Schollmeyer, Dieter Laufer, Stefan |
author_facet | Jahns, Hartmut Koch, Pierre Schollmeyer, Dieter Laufer, Stefan |
author_sort | Jahns, Hartmut |
collection | PubMed |
description | In the title compound, C(20)H(14)FN(3)O, the quinoxaline system makes dihedral angles of 32.38 (7) and 48.04 (7)° with the 4-fluorophenyl and pyridine rings, respectively. The 4-fluorophenyl ring makes a dihedral angle of 57.77 (9)° with the pyridine ring. In the crystal, the molecules form dimeric C—H⋯N hydrogen-bonded R (2) (2)(20) ring motifs lying about crystallographic inversion centers. The dimeric units stack via π–π interactions between methoxyphenyl rings and pyridine–fluorophenyl rings with centroid–centroid distances of 3.720 (1) and 3.823 (1) Å, respectively. The respective average perpendicular distances are 3.421 and 3.378 Å, with dihedral angles between the rings of 1.31 (9) and 11.64 (9)°. |
format | Text |
id | pubmed-2969274 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29692742010-12-30 3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline Jahns, Hartmut Koch, Pierre Schollmeyer, Dieter Laufer, Stefan Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(14)FN(3)O, the quinoxaline system makes dihedral angles of 32.38 (7) and 48.04 (7)° with the 4-fluorophenyl and pyridine rings, respectively. The 4-fluorophenyl ring makes a dihedral angle of 57.77 (9)° with the pyridine ring. In the crystal, the molecules form dimeric C—H⋯N hydrogen-bonded R (2) (2)(20) ring motifs lying about crystallographic inversion centers. The dimeric units stack via π–π interactions between methoxyphenyl rings and pyridine–fluorophenyl rings with centroid–centroid distances of 3.720 (1) and 3.823 (1) Å, respectively. The respective average perpendicular distances are 3.421 and 3.378 Å, with dihedral angles between the rings of 1.31 (9) and 11.64 (9)°. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969274/ /pubmed/21582893 http://dx.doi.org/10.1107/S1600536809022119 Text en © Jahns et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Jahns, Hartmut Koch, Pierre Schollmeyer, Dieter Laufer, Stefan 3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline |
title | 3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline |
title_full | 3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline |
title_fullStr | 3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline |
title_full_unstemmed | 3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline |
title_short | 3-(4-Fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline |
title_sort | 3-(4-fluorophenyl)-6-methoxy-2-(4-pyridyl)quinoxaline |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969274/ https://www.ncbi.nlm.nih.gov/pubmed/21582893 http://dx.doi.org/10.1107/S1600536809022119 |
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