Hydroxonium creatininium bis­(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))nickel­ate(II) trihydrate

The title compound, (C(4)H(8)N(3)O)(H(3)O)[Ni(C(7)H(3)NO(4))(2)]·3H(2)O, exhibits isotypism with its Co(II) analogue. All intramolecular distances and angles are similar for the two structures. This applies also for the intermolecular forces, consisting of O—H⋯O and N—H⋯O hydrogen bonds and π–π inte...

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Detalles Bibliográficos
Autores principales: Attar Gharamaleki, Jafar, Aghabozorg, Hossein, Derikvand, Zohreh, Yousefi, Mohammad
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969276/
https://www.ncbi.nlm.nih.gov/pubmed/21582744
http://dx.doi.org/10.1107/S1600536809022053
Descripción
Sumario:The title compound, (C(4)H(8)N(3)O)(H(3)O)[Ni(C(7)H(3)NO(4))(2)]·3H(2)O, exhibits isotypism with its Co(II) analogue. All intramolecular distances and angles are similar for the two structures. This applies also for the intermolecular forces, consisting of O—H⋯O and N—H⋯O hydrogen bonds and π–π interactions [with centroid–centroid distances of 3.428 (2) and 3.579 (2) Å], that lead to a cohesion of the structure.

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