Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III)

In the title compound, [Tb(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the 7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­iso­quin­oline (L(RR)) ligand coordinates to Tb(III) through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenyl­propan...

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Autores principales: Chen, Lei-Qi, Guo, Jian-Nan, Xuan, Wei-Min, Lin, Yi-Ji, Zhang, Hui
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969283/
https://www.ncbi.nlm.nih.gov/pubmed/21582651
http://dx.doi.org/10.1107/S1600536809019783
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author Chen, Lei-Qi
Guo, Jian-Nan
Xuan, Wei-Min
Lin, Yi-Ji
Zhang, Hui
author_facet Chen, Lei-Qi
Guo, Jian-Nan
Xuan, Wei-Min
Lin, Yi-Ji
Zhang, Hui
author_sort Chen, Lei-Qi
collection PubMed
description In the title compound, [Tb(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the 7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­iso­quin­oline (L(RR)) ligand coordinates to Tb(III) through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenyl­propane-1,3-dione (dbm) ligands, forming enanti­omerically pure [Tb(dbm)(3) L(RR)]. The Tb(III) atom is located in a distorted square anti­prism of eight coordinating atoms (six O and two N atoms).
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spelling pubmed-29692832010-12-30 Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III) Chen, Lei-Qi Guo, Jian-Nan Xuan, Wei-Min Lin, Yi-Ji Zhang, Hui Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Tb(C(15)H(11)O(2))(3)(C(17)H(18)N(2))], the 7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­iso­quin­oline (L(RR)) ligand coordinates to Tb(III) through the two N atoms of the heterocycle. The metal centre is also chelated by three deprotonated 1,3-diphenyl­propane-1,3-dione (dbm) ligands, forming enanti­omerically pure [Tb(dbm)(3) L(RR)]. The Tb(III) atom is located in a distorted square anti­prism of eight coordinating atoms (six O and two N atoms). International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969283/ /pubmed/21582651 http://dx.doi.org/10.1107/S1600536809019783 Text en © Chen et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Chen, Lei-Qi
Guo, Jian-Nan
Xuan, Wei-Min
Lin, Yi-Ji
Zhang, Hui
Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III)
title Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III)
title_full Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III)
title_fullStr Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III)
title_full_unstemmed Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III)
title_short Tris(dibenzoyl­methanido-κ(2) O,O′)[(6R,8R)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) N,N′]terbium(III)
title_sort tris(dibenzoyl­methanido-κ(2) o,o′)[(6r,8r)-(−)-7,7-dimethyl-3-(2-pyrid­yl)-5,6,7,8-tetra­hydro-6,8-methano­isoquinoline-κ(2) n,n′]terbium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969283/
https://www.ncbi.nlm.nih.gov/pubmed/21582651
http://dx.doi.org/10.1107/S1600536809019783
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