Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)

The title mixed-ligand oxidovanadium(IV) compound, [VO(C(5)H(7)O(2))(2)(C(8)H(9)N(3))], contains a V(IV) atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the en...

Descripción completa

Detalles Bibliográficos
Autores principales: Kadirova, Zukhra Ch., Rahmonova, Dilnoza S., Talipov, Samat A., Ashurov, Jamshid M., Parpiev, Nusrat A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969291/
https://www.ncbi.nlm.nih.gov/pubmed/21582741
http://dx.doi.org/10.1107/S1600536809023113
Descripción
Sumario:The title mixed-ligand oxidovanadium(IV) compound, [VO(C(5)H(7)O(2))(2)(C(8)H(9)N(3))], contains a V(IV) atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intra­molecular hydrogen bonds between the exo-NH(2) group H atoms and acetyl­acetonate O atoms stabilize the crystal structure.

Ejemplares similares