Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)

The title mixed-ligand oxidovanadium(IV) compound, [VO(C(5)H(7)O(2))(2)(C(8)H(9)N(3))], contains a V(IV) atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the en...

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Autores principales: Kadirova, Zukhra Ch., Rahmonova, Dilnoza S., Talipov, Samat A., Ashurov, Jamshid M., Parpiev, Nusrat A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969291/
https://www.ncbi.nlm.nih.gov/pubmed/21582741
http://dx.doi.org/10.1107/S1600536809023113
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author Kadirova, Zukhra Ch.
Rahmonova, Dilnoza S.
Talipov, Samat A.
Ashurov, Jamshid M.
Parpiev, Nusrat A.
author_facet Kadirova, Zukhra Ch.
Rahmonova, Dilnoza S.
Talipov, Samat A.
Ashurov, Jamshid M.
Parpiev, Nusrat A.
author_sort Kadirova, Zukhra Ch.
collection PubMed
description The title mixed-ligand oxidovanadium(IV) compound, [VO(C(5)H(7)O(2))(2)(C(8)H(9)N(3))], contains a V(IV) atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intra­molecular hydrogen bonds between the exo-NH(2) group H atoms and acetyl­acetonate O atoms stabilize the crystal structure.
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spelling pubmed-29692912010-12-30 Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV) Kadirova, Zukhra Ch. Rahmonova, Dilnoza S. Talipov, Samat A. Ashurov, Jamshid M. Parpiev, Nusrat A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mixed-ligand oxidovanadium(IV) compound, [VO(C(5)H(7)O(2))(2)(C(8)H(9)N(3))], contains a V(IV) atom in a distorted octahedral coordination, which is typical for such complexes. The vanadyl group and the N-heterocyclic ligand are cis to each other. The coordination bond is located at the endocyclic N atom of the benzimidazole ligand. Intra­molecular hydrogen bonds between the exo-NH(2) group H atoms and acetyl­acetonate O atoms stabilize the crystal structure. International Union of Crystallography 2009-06-24 /pmc/articles/PMC2969291/ /pubmed/21582741 http://dx.doi.org/10.1107/S1600536809023113 Text en © Kadirova et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kadirova, Zukhra Ch.
Rahmonova, Dilnoza S.
Talipov, Samat A.
Ashurov, Jamshid M.
Parpiev, Nusrat A.
Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)
title Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)
title_full Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)
title_fullStr Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)
title_full_unstemmed Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)
title_short Bis(acetyl­acetonato-κ(2) O,O′)(2-amino-1-methyl-1H-benzimidazole-κN (3))oxido­vanadium(IV)
title_sort bis(acetyl­acetonato-κ(2) o,o′)(2-amino-1-methyl-1h-benzimidazole-κn (3))oxido­vanadium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969291/
https://www.ncbi.nlm.nih.gov/pubmed/21582741
http://dx.doi.org/10.1107/S1600536809023113
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AT ashurovjamshidm bisacetylacetonatok2oo2amino1methyl1hbenzimidazolekn3oxidovanadiumiv
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