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Dichloridobis(phenanthridine-κN)zinc(II)

In the mol­ecule of the title compound, [ZnCl(2)(C(13)H(9)N)(2)], the Zn(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from two phenanthridine ligands and by two terminal Cl atoms. The dihedral angle between the planes of the phenanthridine ring systems is 69....

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Autores principales: Khoshtarkib, Zeinab, Ebadi, Amin, Alizadeh, Robabeh, Ahmadi, Roya, Amani, Vahid
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969295/
https://www.ncbi.nlm.nih.gov/pubmed/21582680
http://dx.doi.org/10.1107/S160053680901959X
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author Khoshtarkib, Zeinab
Ebadi, Amin
Alizadeh, Robabeh
Ahmadi, Roya
Amani, Vahid
author_facet Khoshtarkib, Zeinab
Ebadi, Amin
Alizadeh, Robabeh
Ahmadi, Roya
Amani, Vahid
author_sort Khoshtarkib, Zeinab
collection PubMed
description In the mol­ecule of the title compound, [ZnCl(2)(C(13)H(9)N)(2)], the Zn(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from two phenanthridine ligands and by two terminal Cl atoms. The dihedral angle between the planes of the phenanthridine ring systems is 69.92 (3)°. An intra­molecular C—H⋯Cl inter­action results in the formation of a planar five-membered ring, which is oriented at a dihedral angle of 8.32 (3)° with respect to the adjacent phenanthridine ring system. In the crystal structure, π–π contacts between the phenanthridine systems [centroid–centroid distances = 3.839 (2), 3.617 (1) and 3.682 (1) Å] may stabilize the structure. Two weak C—H⋯π inter­actions are also found.
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spelling pubmed-29692952010-12-30 Dichloridobis(phenanthridine-κN)zinc(II) Khoshtarkib, Zeinab Ebadi, Amin Alizadeh, Robabeh Ahmadi, Roya Amani, Vahid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mol­ecule of the title compound, [ZnCl(2)(C(13)H(9)N)(2)], the Zn(II) atom is four-coordinated in a distorted tetra­hedral configuration by two N atoms from two phenanthridine ligands and by two terminal Cl atoms. The dihedral angle between the planes of the phenanthridine ring systems is 69.92 (3)°. An intra­molecular C—H⋯Cl inter­action results in the formation of a planar five-membered ring, which is oriented at a dihedral angle of 8.32 (3)° with respect to the adjacent phenanthridine ring system. In the crystal structure, π–π contacts between the phenanthridine systems [centroid–centroid distances = 3.839 (2), 3.617 (1) and 3.682 (1) Å] may stabilize the structure. Two weak C—H⋯π inter­actions are also found. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969295/ /pubmed/21582680 http://dx.doi.org/10.1107/S160053680901959X Text en © Khoshtarkib et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khoshtarkib, Zeinab
Ebadi, Amin
Alizadeh, Robabeh
Ahmadi, Roya
Amani, Vahid
Dichloridobis(phenanthridine-κN)zinc(II)
title Dichloridobis(phenanthridine-κN)zinc(II)
title_full Dichloridobis(phenanthridine-κN)zinc(II)
title_fullStr Dichloridobis(phenanthridine-κN)zinc(II)
title_full_unstemmed Dichloridobis(phenanthridine-κN)zinc(II)
title_short Dichloridobis(phenanthridine-κN)zinc(II)
title_sort dichloridobis(phenanthridine-κn)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969295/
https://www.ncbi.nlm.nih.gov/pubmed/21582680
http://dx.doi.org/10.1107/S160053680901959X
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