2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide)

In the title compound, C(18)H(16)N(2)O(2)S(2), the benzene ring makes dihedral angles of 7.41 and 86.59° with the two outer pyridine N-oxygen rings. Two short intramolecular C—H⋯S contacts occur. The crystal packing is stabilized by C—H⋯O hydrogen bonds, C—H⋯π inter­actions and weak π–π staking inte...

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Detalles Bibliográficos
Autores principales: Zhang, Chao-Yan, Gao, Qian, Cui, Yue, Xie, Ya-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969296/
https://www.ncbi.nlm.nih.gov/pubmed/21582784
http://dx.doi.org/10.1107/S160053680902073X
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author Zhang, Chao-Yan
Gao, Qian
Cui, Yue
Xie, Ya-Bo
author_facet Zhang, Chao-Yan
Gao, Qian
Cui, Yue
Xie, Ya-Bo
author_sort Zhang, Chao-Yan
collection PubMed
description In the title compound, C(18)H(16)N(2)O(2)S(2), the benzene ring makes dihedral angles of 7.41 and 86.59° with the two outer pyridine N-oxygen rings. Two short intramolecular C—H⋯S contacts occur. The crystal packing is stabilized by C—H⋯O hydrogen bonds, C—H⋯π inter­actions and weak π–π staking inter­actions [centroid–centroid distance 3.7596 (7) Å].
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spelling pubmed-29692962010-12-30 2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide) Zhang, Chao-Yan Gao, Qian Cui, Yue Xie, Ya-Bo Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(16)N(2)O(2)S(2), the benzene ring makes dihedral angles of 7.41 and 86.59° with the two outer pyridine N-oxygen rings. Two short intramolecular C—H⋯S contacts occur. The crystal packing is stabilized by C—H⋯O hydrogen bonds, C—H⋯π inter­actions and weak π–π staking inter­actions [centroid–centroid distance 3.7596 (7) Å]. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969296/ /pubmed/21582784 http://dx.doi.org/10.1107/S160053680902073X Text en © Zhang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Chao-Yan
Gao, Qian
Cui, Yue
Xie, Ya-Bo
2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide)
title 2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide)
title_full 2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide)
title_fullStr 2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide)
title_full_unstemmed 2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide)
title_short 2,2′-[o-Phenylenebis(methylenethio)]bis(pyridine N-oxide)
title_sort 2,2′-[o-phenylenebis(methylenethio)]bis(pyridine n-oxide)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969296/
https://www.ncbi.nlm.nih.gov/pubmed/21582784
http://dx.doi.org/10.1107/S160053680902073X
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AT xieyabo 22ophenylenebismethylenethiobispyridinenoxide

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