Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethyl­formamide disolvate

In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa­hedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in e...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Yun, Ruirui, Li, Ke, Tao, Sun, Wang, Kaitong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969297/
https://www.ncbi.nlm.nih.gov/pubmed/21582714
http://dx.doi.org/10.1107/S1600536809022296
Descripción
Sumario:In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octa­hedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in each of the benzyl­benzimidazole units are 78.56 (12), 81.68 (11), 75.76 (10) and 85.78 (9)°. In the crystal structure, there are weak but significant inter­molecular π–π stacking inter­actions with centroid–centroid distances of 3.685 (1) and 3.978 (1) Å.

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