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Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate
In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octahedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in e...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969297/ https://www.ncbi.nlm.nih.gov/pubmed/21582714 http://dx.doi.org/10.1107/S1600536809022296 |
| _version_ | 1782190105498222592 |
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| author | Wu, Huilu Yun, Ruirui Li, Ke Tao, Sun Wang, Kaitong |
| author_facet | Wu, Huilu Yun, Ruirui Li, Ke Tao, Sun Wang, Kaitong |
| author_sort | Wu, Huilu |
| collection | PubMed |
| description | In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octahedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in each of the benzylbenzimidazole units are 78.56 (12), 81.68 (11), 75.76 (10) and 85.78 (9)°. In the crystal structure, there are weak but significant intermolecular π–π stacking interactions with centroid–centroid distances of 3.685 (1) and 3.978 (1) Å. |
| format | Text |
| id | pubmed-2969297 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29692972010-12-30 Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate Wu, Huilu Yun, Ruirui Li, Ke Tao, Sun Wang, Kaitong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO, the Zn(II) ion is coordinated in a distorted octahedral environment involving four equatorial N atoms and two O atoms in axial sites. The dihedral angles between the benzimidazole ring system and the phenyl rings in each of the benzylbenzimidazole units are 78.56 (12), 81.68 (11), 75.76 (10) and 85.78 (9)°. In the crystal structure, there are weak but significant intermolecular π–π stacking interactions with centroid–centroid distances of 3.685 (1) and 3.978 (1) Å. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969297/ /pubmed/21582714 http://dx.doi.org/10.1107/S1600536809022296 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wu, Huilu Yun, Ruirui Li, Ke Tao, Sun Wang, Kaitong Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate |
| title | Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate |
| title_full | Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate |
| title_fullStr | Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate |
| title_full_unstemmed | Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate |
| title_short | Bis[1,3-bis(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]zinc(II) dipicrate dimethylformamide disolvate |
| title_sort | bis[1,3-bis(1-benzyl-1h-benzimidazol-2-yl)-2-oxapropane]zinc(ii) dipicrate dimethylformamide disolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969297/ https://www.ncbi.nlm.nih.gov/pubmed/21582714 http://dx.doi.org/10.1107/S1600536809022296 |
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