Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate

The title compound (NH(4))(4)[Mo(8)O(24)(O(2))(2)(H(2)O)(2)]·4H(2)O, consists of an octa­molybdate cluster with a crystallographic centre of symmetry. The clusters pack in a cubic close packing arrangement defining channels containing water mol­ecules and ammonium cations, which exhibit hydrogen bon...

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Detalles Bibliográficos
Autores principales: Ward, Antony J., Arrow, Gregory J., Maschmeyer, Thomas, Masters, Anthony F., Turner, Peter, Clegg, Jack K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969302/
https://www.ncbi.nlm.nih.gov/pubmed/21582647
http://dx.doi.org/10.1107/S1600536809023460
Descripción
Sumario:The title compound (NH(4))(4)[Mo(8)O(24)(O(2))(2)(H(2)O)(2)]·4H(2)O, consists of an octa­molybdate cluster with a crystallographic centre of symmetry. The clusters pack in a cubic close packing arrangement defining channels containing water mol­ecules and ammonium cations, which exhibit hydrogen bonding with neighbouring clusters. Hydrogen bonding also exists between the coordinated water mol­ecules of one cluster with one of the O atoms of the peroxido fragment in a neighbouring cluster.

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