Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate

The title compound (NH(4))(4)[Mo(8)O(24)(O(2))(2)(H(2)O)(2)]·4H(2)O, consists of an octa­molybdate cluster with a crystallographic centre of symmetry. The clusters pack in a cubic close packing arrangement defining channels containing water mol­ecules and ammonium cations, which exhibit hydrogen bon...

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Detalles Bibliográficos
Autores principales: Ward, Antony J., Arrow, Gregory J., Maschmeyer, Thomas, Masters, Anthony F., Turner, Peter, Clegg, Jack K.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969302/
https://www.ncbi.nlm.nih.gov/pubmed/21582647
http://dx.doi.org/10.1107/S1600536809023460
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author Ward, Antony J.
Arrow, Gregory J.
Maschmeyer, Thomas
Masters, Anthony F.
Turner, Peter
Clegg, Jack K.
author_facet Ward, Antony J.
Arrow, Gregory J.
Maschmeyer, Thomas
Masters, Anthony F.
Turner, Peter
Clegg, Jack K.
author_sort Ward, Antony J.
collection PubMed
description The title compound (NH(4))(4)[Mo(8)O(24)(O(2))(2)(H(2)O)(2)]·4H(2)O, consists of an octa­molybdate cluster with a crystallographic centre of symmetry. The clusters pack in a cubic close packing arrangement defining channels containing water mol­ecules and ammonium cations, which exhibit hydrogen bonding with neighbouring clusters. Hydrogen bonding also exists between the coordinated water mol­ecules of one cluster with one of the O atoms of the peroxido fragment in a neighbouring cluster.
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spelling pubmed-29693022010-12-30 Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate Ward, Antony J. Arrow, Gregory J. Maschmeyer, Thomas Masters, Anthony F. Turner, Peter Clegg, Jack K. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound (NH(4))(4)[Mo(8)O(24)(O(2))(2)(H(2)O)(2)]·4H(2)O, consists of an octa­molybdate cluster with a crystallographic centre of symmetry. The clusters pack in a cubic close packing arrangement defining channels containing water mol­ecules and ammonium cations, which exhibit hydrogen bonding with neighbouring clusters. Hydrogen bonding also exists between the coordinated water mol­ecules of one cluster with one of the O atoms of the peroxido fragment in a neighbouring cluster. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969302/ /pubmed/21582647 http://dx.doi.org/10.1107/S1600536809023460 Text en © Ward et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Ward, Antony J.
Arrow, Gregory J.
Maschmeyer, Thomas
Masters, Anthony F.
Turner, Peter
Clegg, Jack K.
Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate
title Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate
title_full Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate
title_fullStr Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate
title_full_unstemmed Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate
title_short Tetra­ammonium diaqua­diperoxidoocta­molybdate(VI) tetra­hydrate
title_sort tetra­ammonium diaqua­diperoxidoocta­molybdate(vi) tetra­hydrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969302/
https://www.ncbi.nlm.nih.gov/pubmed/21582647
http://dx.doi.org/10.1107/S1600536809023460
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AT mastersanthonyf tetraammoniumdiaquadiperoxidooctamolybdatevitetrahydrate
AT turnerpeter tetraammoniumdiaquadiperoxidooctamolybdatevitetrahydrate
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