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(Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) dimethylformamide solvate
In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetradentate Schiff base ligand and the O atom of one dimethylformamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethylformami...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969304/ https://www.ncbi.nlm.nih.gov/pubmed/21582693 http://dx.doi.org/10.1107/S160053680902162X |
| _version_ | 1782190107704426496 |
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| author | Wu, Yu Xie, Bin Zou, Li-Ke Wu, Wei-Ping Lu, Lu |
| author_facet | Wu, Yu Xie, Bin Zou, Li-Ke Wu, Wei-Ping Lu, Lu |
| author_sort | Wu, Yu |
| collection | PubMed |
| description | In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetradentate Schiff base ligand and the O atom of one dimethylformamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethylformamide solvent molecule is disordered over two sets of positions with occupancies of 0.741 (4) and 0.259 (4). The crystal packing is stabilized by C—H⋯O interactions. |
| format | Text |
| id | pubmed-2969304 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29693042010-12-30 (Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) dimethylformamide solvate Wu, Yu Xie, Bin Zou, Li-Ke Wu, Wei-Ping Lu, Lu Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(20)H(10)Br(4)N(2)O(2))(C(3)H(7)NO)]·C(3)H(7)NO, the Cu(II) ion is coordinated by two N atoms and two O atoms from a tetradentate Schiff base ligand and the O atom of one dimethylformamide ligand in an almost square-pyramidal geometry. The uncoordinated dimethylformamide solvent molecule is disordered over two sets of positions with occupancies of 0.741 (4) and 0.259 (4). The crystal packing is stabilized by C—H⋯O interactions. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969304/ /pubmed/21582693 http://dx.doi.org/10.1107/S160053680902162X Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wu, Yu Xie, Bin Zou, Li-Ke Wu, Wei-Ping Lu, Lu (Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4) O,N,N′,O′}copper(II) dimethylformamide solvate |
| title | (Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}copper(II) dimethylformamide solvate |
| title_full | (Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}copper(II) dimethylformamide solvate |
| title_fullStr | (Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}copper(II) dimethylformamide solvate |
| title_full_unstemmed | (Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}copper(II) dimethylformamide solvate |
| title_short | (Dimethylformamide-κO){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
O,N,N′,O′}copper(II) dimethylformamide solvate |
| title_sort | (dimethylformamide-κo){4,4′,6,6′-tetrabromo-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ(4)
o,n,n′,o′}copper(ii) dimethylformamide solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969304/ https://www.ncbi.nlm.nih.gov/pubmed/21582693 http://dx.doi.org/10.1107/S160053680902162X |
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