catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate]

In the crystal structure of the title complex, {[Mn(C(11)H(14)NO(2))(2)(H(2)O)(3)]·2H(2)O}(n), the two independent Mn(II) atoms are located on a centre of symmetry and coordinated by two 4-(diethyl­amino)benzoate (DEAB) anions and two water mol­ecules in the basal plane while another water mol­ecule...

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Autores principales: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Aybirdi, Özgür, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969307/
https://www.ncbi.nlm.nih.gov/pubmed/21582685
http://dx.doi.org/10.1107/S1600536809021060
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author Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_facet Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
author_sort Hökelek, Tuncer
collection PubMed
description In the crystal structure of the title complex, {[Mn(C(11)H(14)NO(2))(2)(H(2)O)(3)]·2H(2)O}(n), the two independent Mn(II) atoms are located on a centre of symmetry and coordinated by two 4-(diethyl­amino)benzoate (DEAB) anions and two water mol­ecules in the basal plane while another water mol­ecule bridges the Mn atoms in the apical directions, forming polymeric chains. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 11.33 (13) and 10.90 (9)° and the benzene rings are oriented at a dihedral angle of 67.88 (6)°. The uncoordinated water mol­ecules link the carboxyl­ate groups and coordinated water mol­ecules via O—H⋯O hydrogen bonding. Weak C—H⋯π inter­actions are also found in the crystal structure.
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spelling pubmed-29693072010-12-30 catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate] Hökelek, Tuncer Dal, Hakan Tercan, Barış Aybirdi, Özgür Necefoğlu, Hacali Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the crystal structure of the title complex, {[Mn(C(11)H(14)NO(2))(2)(H(2)O)(3)]·2H(2)O}(n), the two independent Mn(II) atoms are located on a centre of symmetry and coordinated by two 4-(diethyl­amino)benzoate (DEAB) anions and two water mol­ecules in the basal plane while another water mol­ecule bridges the Mn atoms in the apical directions, forming polymeric chains. The dihedral angles between the carboxyl­ate groups and the adjacent benzene rings are 11.33 (13) and 10.90 (9)° and the benzene rings are oriented at a dihedral angle of 67.88 (6)°. The uncoordinated water mol­ecules link the carboxyl­ate groups and coordinated water mol­ecules via O—H⋯O hydrogen bonding. Weak C—H⋯π inter­actions are also found in the crystal structure. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969307/ /pubmed/21582685 http://dx.doi.org/10.1107/S1600536809021060 Text en © Hökelek et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Aybirdi, Özgür
Necefoğlu, Hacali
catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate]
title catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate]
title_full catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate]
title_fullStr catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate]
title_full_unstemmed catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate]
title_short catena-Poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κO]manganese(II)]-μ-aqua] dihydrate]
title_sort catena-poly[[[diaqua­bis[4-(diethyl­amino)benzoato-κo]manganese(ii)]-μ-aqua] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969307/
https://www.ncbi.nlm.nih.gov/pubmed/21582685
http://dx.doi.org/10.1107/S1600536809021060
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