Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]

The title compound, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2))(2)](n), was synthesized by the reaction of 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The Cd(II) atom is seven-coordinated in a distorted penta­gonal-bipyramidal configuration by five O atoms from carboxy...

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Detalles Bibliográficos
Autores principales: Wang, Na, Wang, Yan-Jun, Lin, Qiu-Yue
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969310/
https://www.ncbi.nlm.nih.gov/pubmed/21582710
http://dx.doi.org/10.1107/S1600536809021801
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author Wang, Na
Wang, Yan-Jun
Lin, Qiu-Yue
author_facet Wang, Na
Wang, Yan-Jun
Lin, Qiu-Yue
author_sort Wang, Na
collection PubMed
description The title compound, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2))(2)](n), was synthesized by the reaction of 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The Cd(II) atom is seven-coordinated in a distorted penta­gonal-bipyramidal configuration by five O atoms from carboxyl­ate groups of three 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylate ligands and two N atoms from two imidazole ligands. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen-bonding and C—H⋯π inter­actions.
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spelling pubmed-29693102010-12-30 Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)] Wang, Na Wang, Yan-Jun Lin, Qiu-Yue Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(8)H(8)O(5))(C(3)H(4)N(2))(2)](n), was synthesized by the reaction of 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The Cd(II) atom is seven-coordinated in a distorted penta­gonal-bipyramidal configuration by five O atoms from carboxyl­ate groups of three 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylate ligands and two N atoms from two imidazole ligands. The crystal structure is stabilized by N—H⋯O and C—H⋯O hydrogen-bonding and C—H⋯π inter­actions. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969310/ /pubmed/21582710 http://dx.doi.org/10.1107/S1600536809021801 Text en © Wang et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Na
Wang, Yan-Jun
Lin, Qiu-Yue
Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]
title Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]
title_full Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]
title_fullStr Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]
title_full_unstemmed Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]
title_short Poly[bis­(1H-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(II)]
title_sort poly[bis­(1h-imidazole)(μ(3)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969310/
https://www.ncbi.nlm.nih.gov/pubmed/21582710
http://dx.doi.org/10.1107/S1600536809021801
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AT wangyanjun polybis1himidazolem37oxabicyclo221heptane23dicarboxylatocadmiumii
AT linqiuyue polybis1himidazolem37oxabicyclo221heptane23dicarboxylatocadmiumii

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