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Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)

In the title compound, [Ni(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO·0.25CH(3)CH(2)OH, the Ni(II) ion is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms from two tridendate 1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane ligands. The crystal struct...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Yun, Ruirui, Li, Ke, Wang, Kaitong, Huang, Xingcai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969312/
https://www.ncbi.nlm.nih.gov/pubmed/21582688
http://dx.doi.org/10.1107/S1600536809021163
Descripción
Sumario:In the title compound, [Ni(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO·0.25CH(3)CH(2)OH, the Ni(II) ion is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms from two tridendate 1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane ligands. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds and weak π–π stacking inter­actions [centroid–centroid distance 3.501 (3) Å]. As well as the cation, two anions and two dimethyl­formamide solvent mol­ecules, the asymmetric unit also contains an ethanol solvent molecule with 0.25 occupancy.