Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)

In the title compound, [Ni(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO·0.25CH(3)CH(2)OH, the Ni(II) ion is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms from two tridendate 1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane ligands. The crystal struct...

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Detalles Bibliográficos
Autores principales: Wu, Huilu, Yun, Ruirui, Li, Ke, Wang, Kaitong, Huang, Xingcai
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969312/
https://www.ncbi.nlm.nih.gov/pubmed/21582688
http://dx.doi.org/10.1107/S1600536809021163
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author Wu, Huilu
Yun, Ruirui
Li, Ke
Wang, Kaitong
Huang, Xingcai
author_facet Wu, Huilu
Yun, Ruirui
Li, Ke
Wang, Kaitong
Huang, Xingcai
author_sort Wu, Huilu
collection PubMed
description In the title compound, [Ni(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO·0.25CH(3)CH(2)OH, the Ni(II) ion is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms from two tridendate 1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane ligands. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds and weak π–π stacking inter­actions [centroid–centroid distance 3.501 (3) Å]. As well as the cation, two anions and two dimethyl­formamide solvent mol­ecules, the asymmetric unit also contains an ethanol solvent molecule with 0.25 occupancy.
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spelling pubmed-29693122010-12-30 Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25) Wu, Huilu Yun, Ruirui Li, Ke Wang, Kaitong Huang, Xingcai Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(30)H(26)N(4)O)(2)](C(6)H(2)N(3)O(7))(2)·2C(3)H(7)NO·0.25CH(3)CH(2)OH, the Ni(II) ion is coordinated in a distorted octa­hedral environment by four N atoms and two O atoms from two tridendate 1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane ligands. The crystal structure is stabilized by weak inter­molecular C—H⋯O hydrogen bonds and weak π–π stacking inter­actions [centroid–centroid distance 3.501 (3) Å]. As well as the cation, two anions and two dimethyl­formamide solvent mol­ecules, the asymmetric unit also contains an ethanol solvent molecule with 0.25 occupancy. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969312/ /pubmed/21582688 http://dx.doi.org/10.1107/S1600536809021163 Text en © Wu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wu, Huilu
Yun, Ruirui
Li, Ke
Wang, Kaitong
Huang, Xingcai
Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)
title Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)
title_full Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)
title_fullStr Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)
title_full_unstemmed Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)
title_short Bis[1,3-bis­(1-benzyl-1H-benzimidazol-2-yl)-2-oxapropane]nickel(II) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)
title_sort bis[1,3-bis­(1-benzyl-1h-benzimidazol-2-yl)-2-oxapropane]nickel(ii) dipicrate–dimethyl­formamide–ethanol (1/2/0.25)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969312/
https://www.ncbi.nlm.nih.gov/pubmed/21582688
http://dx.doi.org/10.1107/S1600536809021163
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