2-(1H-Benzotriazol-1-yl)acetohydrazide

The title compound, C(8)H(9)N(5)O, was synthesized by the reaction of ethyl 2-(benzotriazol-1-yl)acetate with hydrazine hydrate in ethanol. In the amide group, the C—N bond is relatively short [1.3283 (16) Å], suggesting some degree of electronic delocalization in the mol­ecule. In the crystal struc...

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Detalles Bibliográficos
Autores principales: Zhang, Yan-Xia, Shi, Zhi-Qiang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969314/
https://www.ncbi.nlm.nih.gov/pubmed/21582826
http://dx.doi.org/10.1107/S1600536809021199
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author Zhang, Yan-Xia
Shi, Zhi-Qiang
author_facet Zhang, Yan-Xia
Shi, Zhi-Qiang
author_sort Zhang, Yan-Xia
collection PubMed
description The title compound, C(8)H(9)N(5)O, was synthesized by the reaction of ethyl 2-(benzotriazol-1-yl)acetate with hydrazine hydrate in ethanol. In the amide group, the C—N bond is relatively short [1.3283 (16) Å], suggesting some degree of electronic delocalization in the mol­ecule. In the crystal structure, mol­ecules are linked into infinite chains along the a axis by inter­molecular O—H⋯N hydrogen bonding.
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spelling pubmed-29693142010-12-30 2-(1H-Benzotriazol-1-yl)acetohydrazide Zhang, Yan-Xia Shi, Zhi-Qiang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(8)H(9)N(5)O, was synthesized by the reaction of ethyl 2-(benzotriazol-1-yl)acetate with hydrazine hydrate in ethanol. In the amide group, the C—N bond is relatively short [1.3283 (16) Å], suggesting some degree of electronic delocalization in the mol­ecule. In the crystal structure, mol­ecules are linked into infinite chains along the a axis by inter­molecular O—H⋯N hydrogen bonding. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969314/ /pubmed/21582826 http://dx.doi.org/10.1107/S1600536809021199 Text en © Zhang and Shi 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Yan-Xia
Shi, Zhi-Qiang
2-(1H-Benzotriazol-1-yl)acetohydrazide
title 2-(1H-Benzotriazol-1-yl)acetohydrazide
title_full 2-(1H-Benzotriazol-1-yl)acetohydrazide
title_fullStr 2-(1H-Benzotriazol-1-yl)acetohydrazide
title_full_unstemmed 2-(1H-Benzotriazol-1-yl)acetohydrazide
title_short 2-(1H-Benzotriazol-1-yl)acetohydrazide
title_sort 2-(1h-benzotriazol-1-yl)acetohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969314/
https://www.ncbi.nlm.nih.gov/pubmed/21582826
http://dx.doi.org/10.1107/S1600536809021199
work_keys_str_mv AT zhangyanxia 21hbenzotriazol1ylacetohydrazide
AT shizhiqiang 21hbenzotriazol1ylacetohydrazide

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