Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)

The title mol­ecule, [Sn(C(8)H(3)F(6))(4)], lies on a twofold rotation axis with the Sn(IV) ion in a distorted tetra­hedral coordination environment. Both –CF(3) groups attached to one of the unique benzene rings are disordered over two sets of sites, with the ratios of refined occupancies being 0.7...

Descripción completa

Detalles Bibliográficos
Autores principales: Foucher, Daniel, Miles, Damion, Lough, Alan J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969316/
https://www.ncbi.nlm.nih.gov/pubmed/21582650
http://dx.doi.org/10.1107/S1600536809019588
Descripción
Sumario:The title mol­ecule, [Sn(C(8)H(3)F(6))(4)], lies on a twofold rotation axis with the Sn(IV) ion in a distorted tetra­hedral coordination environment. Both –CF(3) groups attached to one of the unique benzene rings are disordered over two sets of sites, with the ratios of refined occupancies being 0.719 (14):0.281 (14) and 0.63 (5):0.37 (5).

Ejemplares similares