Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)

The title mol­ecule, [Sn(C(8)H(3)F(6))(4)], lies on a twofold rotation axis with the Sn(IV) ion in a distorted tetra­hedral coordination environment. Both –CF(3) groups attached to one of the unique benzene rings are disordered over two sets of sites, with the ratios of refined occupancies being 0.7...

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Detalles Bibliográficos
Autores principales: Foucher, Daniel, Miles, Damion, Lough, Alan J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969316/
https://www.ncbi.nlm.nih.gov/pubmed/21582650
http://dx.doi.org/10.1107/S1600536809019588
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author Foucher, Daniel
Miles, Damion
Lough, Alan J.
author_facet Foucher, Daniel
Miles, Damion
Lough, Alan J.
author_sort Foucher, Daniel
collection PubMed
description The title mol­ecule, [Sn(C(8)H(3)F(6))(4)], lies on a twofold rotation axis with the Sn(IV) ion in a distorted tetra­hedral coordination environment. Both –CF(3) groups attached to one of the unique benzene rings are disordered over two sets of sites, with the ratios of refined occupancies being 0.719 (14):0.281 (14) and 0.63 (5):0.37 (5).
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spelling pubmed-29693162010-12-30 Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV) Foucher, Daniel Miles, Damion Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mol­ecule, [Sn(C(8)H(3)F(6))(4)], lies on a twofold rotation axis with the Sn(IV) ion in a distorted tetra­hedral coordination environment. Both –CF(3) groups attached to one of the unique benzene rings are disordered over two sets of sites, with the ratios of refined occupancies being 0.719 (14):0.281 (14) and 0.63 (5):0.37 (5). International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969316/ /pubmed/21582650 http://dx.doi.org/10.1107/S1600536809019588 Text en © Foucher et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Foucher, Daniel
Miles, Damion
Lough, Alan J.
Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)
title Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)
title_full Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)
title_fullStr Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)
title_full_unstemmed Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)
title_short Tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(IV)
title_sort tetra­kis[3,5-bis­(trifluoro­meth­yl)phenyl]tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969316/
https://www.ncbi.nlm.nih.gov/pubmed/21582650
http://dx.doi.org/10.1107/S1600536809019588
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AT milesdamion tetrakis35bistrifluoromethylphenyltiniv
AT loughalanj tetrakis35bistrifluoromethylphenyltiniv

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