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Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate
The asymmetric unit of the title compound, [Ni(C(3)H(10)N(2))(2)(H(2)O)(2)](C(4)O(4))·4H(2)O, contains one-half of the diaquabis(1,3-propanediamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water molecules. In the cation, the Ni(II) atom is located on...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969320/ https://www.ncbi.nlm.nih.gov/pubmed/21582677 http://dx.doi.org/10.1107/S160053680902087X |
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author | Temel, Ersin Erer, Hakan Yeşilel, Okan Zafer Büyükgüngör, Orhan |
author_facet | Temel, Ersin Erer, Hakan Yeşilel, Okan Zafer Büyükgüngör, Orhan |
author_sort | Temel, Ersin |
collection | PubMed |
description | The asymmetric unit of the title compound, [Ni(C(3)H(10)N(2))(2)(H(2)O)(2)](C(4)O(4))·4H(2)O, contains one-half of the diaquabis(1,3-propanediamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water molecules. In the cation, the Ni(II) atom is located on a crystallographic inversion centre and has a slightly distorted octahedral coordination geometry. The six-membered chelate ring adopts a chair conformation. O—H⋯O hydrogen bonds link the cation and anion through the water molecule, while N—H⋯O hydrogen bonds link the cation and anion and cation and water molecules. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a three-dimensional network structure. |
format | Text |
id | pubmed-2969320 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29693202010-12-30 Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate Temel, Ersin Erer, Hakan Yeşilel, Okan Zafer Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(3)H(10)N(2))(2)(H(2)O)(2)](C(4)O(4))·4H(2)O, contains one-half of the diaquabis(1,3-propanediamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water molecules. In the cation, the Ni(II) atom is located on a crystallographic inversion centre and has a slightly distorted octahedral coordination geometry. The six-membered chelate ring adopts a chair conformation. O—H⋯O hydrogen bonds link the cation and anion through the water molecule, while N—H⋯O hydrogen bonds link the cation and anion and cation and water molecules. In the crystal structure, intermolecular O—H⋯O and N—H⋯O hydrogen bonds link the molecules into a three-dimensional network structure. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969320/ /pubmed/21582677 http://dx.doi.org/10.1107/S160053680902087X Text en © Temel et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Temel, Ersin Erer, Hakan Yeşilel, Okan Zafer Büyükgüngör, Orhan Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
title | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
title_full | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
title_fullStr | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
title_full_unstemmed | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
title_short | Diaquabis(1,3-propanediamine)nickel(II) squarate tetrahydrate |
title_sort | diaquabis(1,3-propanediamine)nickel(ii) squarate tetrahydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969320/ https://www.ncbi.nlm.nih.gov/pubmed/21582677 http://dx.doi.org/10.1107/S160053680902087X |
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