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Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate

The asymmetric unit of the title compound, [Ni(C(3)H(10)N(2))(2)(H(2)O)(2)](C(4)O(4))·4H(2)O, contains one-half of the diaqua­bis(1,3-propane­diamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water mol­ecules. In the cation, the Ni(II) atom is located on...

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Autores principales: Temel, Ersin, Erer, Hakan, Yeşilel, Okan Zafer, Büyükgüngör, Orhan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969320/
https://www.ncbi.nlm.nih.gov/pubmed/21582677
http://dx.doi.org/10.1107/S160053680902087X
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author Temel, Ersin
Erer, Hakan
Yeşilel, Okan Zafer
Büyükgüngör, Orhan
author_facet Temel, Ersin
Erer, Hakan
Yeşilel, Okan Zafer
Büyükgüngör, Orhan
author_sort Temel, Ersin
collection PubMed
description The asymmetric unit of the title compound, [Ni(C(3)H(10)N(2))(2)(H(2)O)(2)](C(4)O(4))·4H(2)O, contains one-half of the diaqua­bis(1,3-propane­diamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water mol­ecules. In the cation, the Ni(II) atom is located on a crystallographic inversion centre and has a slightly distorted octa­hedral coordination geometry. The six-membered chelate ring adopts a chair conformation. O—H⋯O hydrogen bonds link the cation and anion through the water mol­ecule, while N—H⋯O hydrogen bonds link the cation and anion and cation and water mol­ecules. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network structure.
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spelling pubmed-29693202010-12-30 Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate Temel, Ersin Erer, Hakan Yeşilel, Okan Zafer Büyükgüngör, Orhan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Ni(C(3)H(10)N(2))(2)(H(2)O)(2)](C(4)O(4))·4H(2)O, contains one-half of the diaqua­bis(1,3-propane­diamine)nickel(II) cation, one-half of the centrosymmetric squarate anion and two uncoordinated water mol­ecules. In the cation, the Ni(II) atom is located on a crystallographic inversion centre and has a slightly distorted octa­hedral coordination geometry. The six-membered chelate ring adopts a chair conformation. O—H⋯O hydrogen bonds link the cation and anion through the water mol­ecule, while N—H⋯O hydrogen bonds link the cation and anion and cation and water mol­ecules. In the crystal structure, inter­molecular O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a three-dimensional network structure. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969320/ /pubmed/21582677 http://dx.doi.org/10.1107/S160053680902087X Text en © Temel et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Temel, Ersin
Erer, Hakan
Yeşilel, Okan Zafer
Büyükgüngör, Orhan
Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate
title Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate
title_full Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate
title_fullStr Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate
title_full_unstemmed Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate
title_short Diaqua­bis(1,3-propane­diamine)nickel(II) squarate tetrahydrate
title_sort diaqua­bis(1,3-propane­diamine)nickel(ii) squarate tetrahydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969320/
https://www.ncbi.nlm.nih.gov/pubmed/21582677
http://dx.doi.org/10.1107/S160053680902087X
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