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(E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone

In the title compound, C(9)H(10)ClN(3)O, the semicarbazone group is approximately planar, with an r.m.s. deviation from the mean plane of 0.054 (1) Å. The dihedral angle between the least-squares planes through the semicarbazone group and the benzene ring is 30.46 (5)°. In the solid state, mol­ecule...

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Autores principales: Fun, Hoong-Kun, Quah, Ching Kheng, Padaki, Mahesh, Malladi, Shridhar, Isloor, Arun M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969321/
https://www.ncbi.nlm.nih.gov/pubmed/21582900
http://dx.doi.org/10.1107/S160053680902279X
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author Fun, Hoong-Kun
Quah, Ching Kheng
Padaki, Mahesh
Malladi, Shridhar
Isloor, Arun M.
author_facet Fun, Hoong-Kun
Quah, Ching Kheng
Padaki, Mahesh
Malladi, Shridhar
Isloor, Arun M.
author_sort Fun, Hoong-Kun
collection PubMed
description In the title compound, C(9)H(10)ClN(3)O, the semicarbazone group is approximately planar, with an r.m.s. deviation from the mean plane of 0.054 (1) Å. The dihedral angle between the least-squares planes through the semicarbazone group and the benzene ring is 30.46 (5)°. In the solid state, mol­ecules are linked via inter­molecular N—H⋯O and N—H⋯N hydrogen bonds, generating R (2) (2)(9) ring motifs which, together with R (2) (2)(8) ring motifs formed by pairs of inter­molecular N—H⋯O hydrogen bonds, lead to the formation of a seldom-observed mol­ecular trimer. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O hydrogen bonds, further consolidating the crystal structure. Mol­ecules are linked by these inter­molecular inter­actions, forming two-dimensional networks parallel to (100).
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spelling pubmed-29693212010-12-30 (E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone Fun, Hoong-Kun Quah, Ching Kheng Padaki, Mahesh Malladi, Shridhar Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(10)ClN(3)O, the semicarbazone group is approximately planar, with an r.m.s. deviation from the mean plane of 0.054 (1) Å. The dihedral angle between the least-squares planes through the semicarbazone group and the benzene ring is 30.46 (5)°. In the solid state, mol­ecules are linked via inter­molecular N—H⋯O and N—H⋯N hydrogen bonds, generating R (2) (2)(9) ring motifs which, together with R (2) (2)(8) ring motifs formed by pairs of inter­molecular N—H⋯O hydrogen bonds, lead to the formation of a seldom-observed mol­ecular trimer. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O hydrogen bonds, further consolidating the crystal structure. Mol­ecules are linked by these inter­molecular inter­actions, forming two-dimensional networks parallel to (100). International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969321/ /pubmed/21582900 http://dx.doi.org/10.1107/S160053680902279X Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Fun, Hoong-Kun
Quah, Ching Kheng
Padaki, Mahesh
Malladi, Shridhar
Isloor, Arun M.
(E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone
title (E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone
title_full (E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone
title_fullStr (E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone
title_full_unstemmed (E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone
title_short (E)-1-(4-Chloro­phen­yl)ethanone semi­carbazone
title_sort (e)-1-(4-chloro­phen­yl)ethanone semi­carbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969321/
https://www.ncbi.nlm.nih.gov/pubmed/21582900
http://dx.doi.org/10.1107/S160053680902279X
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