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(E)-1-(4-Chlorophenyl)ethanone semicarbazone
In the title compound, C(9)H(10)ClN(3)O, the semicarbazone group is approximately planar, with an r.m.s. deviation from the mean plane of 0.054 (1) Å. The dihedral angle between the least-squares planes through the semicarbazone group and the benzene ring is 30.46 (5)°. In the solid state, molecule...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969321/ https://www.ncbi.nlm.nih.gov/pubmed/21582900 http://dx.doi.org/10.1107/S160053680902279X |
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author | Fun, Hoong-Kun Quah, Ching Kheng Padaki, Mahesh Malladi, Shridhar Isloor, Arun M. |
author_facet | Fun, Hoong-Kun Quah, Ching Kheng Padaki, Mahesh Malladi, Shridhar Isloor, Arun M. |
author_sort | Fun, Hoong-Kun |
collection | PubMed |
description | In the title compound, C(9)H(10)ClN(3)O, the semicarbazone group is approximately planar, with an r.m.s. deviation from the mean plane of 0.054 (1) Å. The dihedral angle between the least-squares planes through the semicarbazone group and the benzene ring is 30.46 (5)°. In the solid state, molecules are linked via intermolecular N—H⋯O and N—H⋯N hydrogen bonds, generating R (2) (2)(9) ring motifs which, together with R (2) (2)(8) ring motifs formed by pairs of intermolecular N—H⋯O hydrogen bonds, lead to the formation of a seldom-observed molecular trimer. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O hydrogen bonds, further consolidating the crystal structure. Molecules are linked by these intermolecular interactions, forming two-dimensional networks parallel to (100). |
format | Text |
id | pubmed-2969321 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29693212010-12-30 (E)-1-(4-Chlorophenyl)ethanone semicarbazone Fun, Hoong-Kun Quah, Ching Kheng Padaki, Mahesh Malladi, Shridhar Isloor, Arun M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(9)H(10)ClN(3)O, the semicarbazone group is approximately planar, with an r.m.s. deviation from the mean plane of 0.054 (1) Å. The dihedral angle between the least-squares planes through the semicarbazone group and the benzene ring is 30.46 (5)°. In the solid state, molecules are linked via intermolecular N—H⋯O and N—H⋯N hydrogen bonds, generating R (2) (2)(9) ring motifs which, together with R (2) (2)(8) ring motifs formed by pairs of intermolecular N—H⋯O hydrogen bonds, lead to the formation of a seldom-observed molecular trimer. Furthermore, N—H⋯O hydrogen bonds form R (2) (1)(7) ring motifs with C—H⋯O hydrogen bonds, further consolidating the crystal structure. Molecules are linked by these intermolecular interactions, forming two-dimensional networks parallel to (100). International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969321/ /pubmed/21582900 http://dx.doi.org/10.1107/S160053680902279X Text en © Fun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Fun, Hoong-Kun Quah, Ching Kheng Padaki, Mahesh Malladi, Shridhar Isloor, Arun M. (E)-1-(4-Chlorophenyl)ethanone semicarbazone |
title | (E)-1-(4-Chlorophenyl)ethanone semicarbazone |
title_full | (E)-1-(4-Chlorophenyl)ethanone semicarbazone |
title_fullStr | (E)-1-(4-Chlorophenyl)ethanone semicarbazone |
title_full_unstemmed | (E)-1-(4-Chlorophenyl)ethanone semicarbazone |
title_short | (E)-1-(4-Chlorophenyl)ethanone semicarbazone |
title_sort | (e)-1-(4-chlorophenyl)ethanone semicarbazone |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969321/ https://www.ncbi.nlm.nih.gov/pubmed/21582900 http://dx.doi.org/10.1107/S160053680902279X |
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