N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide

In the title compound, C(16)H(16)BrNO(4), the dihedral between the planes of the aromatic rings is 7.74 (18)°. The amide group is tilted with respect to the bromo- and meth­oxy-substituted aromatic rings by 36.3 (8) and 35.2 (8)°, respectively. The meta-meth­oxy groups are essentially in-plane with...

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Detalles Bibliográficos
Autores principales: Saeed, Aamer, Hussain, Shahid, Ibrar, Aliya, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969324/
https://www.ncbi.nlm.nih.gov/pubmed/21582773
http://dx.doi.org/10.1107/S1600536809020509
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author Saeed, Aamer
Hussain, Shahid
Ibrar, Aliya
Bolte, Michael
author_facet Saeed, Aamer
Hussain, Shahid
Ibrar, Aliya
Bolte, Michael
author_sort Saeed, Aamer
collection PubMed
description In the title compound, C(16)H(16)BrNO(4), the dihedral between the planes of the aromatic rings is 7.74 (18)°. The amide group is tilted with respect to the bromo- and meth­oxy-substituted aromatic rings by 36.3 (8) and 35.2 (8)°, respectively. The meta-meth­oxy groups are essentially in-plane with the aromatic ring [dihedral angles CH(3)—O—C—C = −4.6 (4) and −2.5 (4)°]. The para-meth­oxy group is markedly displaced from the ring plane [dihedral angle CH(3)—O—C—C = −72.5 (4)°]. The crystal packing is stabilized by N—H⋯O hydrogen bonds linking the mol­ecules into chains running along the b axis.
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spelling pubmed-29693242010-12-30 N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide Saeed, Aamer Hussain, Shahid Ibrar, Aliya Bolte, Michael Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(16)BrNO(4), the dihedral between the planes of the aromatic rings is 7.74 (18)°. The amide group is tilted with respect to the bromo- and meth­oxy-substituted aromatic rings by 36.3 (8) and 35.2 (8)°, respectively. The meta-meth­oxy groups are essentially in-plane with the aromatic ring [dihedral angles CH(3)—O—C—C = −4.6 (4) and −2.5 (4)°]. The para-meth­oxy group is markedly displaced from the ring plane [dihedral angle CH(3)—O—C—C = −72.5 (4)°]. The crystal packing is stabilized by N—H⋯O hydrogen bonds linking the mol­ecules into chains running along the b axis. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969324/ /pubmed/21582773 http://dx.doi.org/10.1107/S1600536809020509 Text en © Saeed et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Saeed, Aamer
Hussain, Shahid
Ibrar, Aliya
Bolte, Michael
N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide
title N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide
title_full N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide
title_fullStr N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide
title_full_unstemmed N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide
title_short N-(3-Bromo­phen­yl)-3,4,5-trimethoxy­benzamide
title_sort n-(3-bromo­phen­yl)-3,4,5-trimethoxy­benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969324/
https://www.ncbi.nlm.nih.gov/pubmed/21582773
http://dx.doi.org/10.1107/S1600536809020509
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