cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate

Both mol­ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa­hedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen bonds.

Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Dai, Yong-Qiang, Tang, Man-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969325/
https://www.ncbi.nlm.nih.gov/pubmed/21582667
http://dx.doi.org/10.1107/S1600536809020042
Descripción
Sumario:Both mol­ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa­hedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen bonds.

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