cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate

Both mol­ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa­hedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen bonds.

Detalles Bibliográficos
Autores principales: Ou, Guang-Chuan, Dai, Yong-Qiang, Tang, Man-Sheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969325/
https://www.ncbi.nlm.nih.gov/pubmed/21582667
http://dx.doi.org/10.1107/S1600536809020042
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author Ou, Guang-Chuan
Dai, Yong-Qiang
Tang, Man-Sheng
author_facet Ou, Guang-Chuan
Dai, Yong-Qiang
Tang, Man-Sheng
author_sort Ou, Guang-Chuan
collection PubMed
description Both mol­ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa­hedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29693252010-12-30 cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate Ou, Guang-Chuan Dai, Yong-Qiang Tang, Man-Sheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Both mol­ecules of the title compound, [Ni(C(2)O(4))(C(16)H(36)N(4))]·C(2)H(2)O(4), are located on a crystallographic twofold rotation axis. The Ni(II) atom shows a distorted octa­hedral geometry. The crystal packing is stabilized by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2009-06-06 /pmc/articles/PMC2969325/ /pubmed/21582667 http://dx.doi.org/10.1107/S1600536809020042 Text en © Ou et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ou, Guang-Chuan
Dai, Yong-Qiang
Tang, Man-Sheng
cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate
title cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate
title_full cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate
title_fullStr cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate
title_full_unstemmed cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate
title_short cis-[(7R,14R)-5,5,7,12,12,14-Hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) N](oxalato-κ(2) O,O′)nickel(II) oxalic acid solvate
title_sort cis-[(7r,14r)-5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­azacyclo­tetra­decane-κ(4) n](oxalato-κ(2) o,o′)nickel(ii) oxalic acid solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969325/
https://www.ncbi.nlm.nih.gov/pubmed/21582667
http://dx.doi.org/10.1107/S1600536809020042
work_keys_str_mv AT ouguangchuan cis7r14r557121214hexamethyl14811tetraazacyclotetradecanek4noxalatok2oonickeliioxalicacidsolvate
AT daiyongqiang cis7r14r557121214hexamethyl14811tetraazacyclotetradecanek4noxalatok2oonickeliioxalicacidsolvate
AT tangmansheng cis7r14r557121214hexamethyl14811tetraazacyclotetradecanek4noxalatok2oonickeliioxalicacidsolvate

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