{Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II)

The asymmetric unit of the title compound, [CoCl(2)(C(18)H(12)N(6)S)], contains one half-mol­ecule situated on a twofold rotation axis which passes through the Co and S atoms. The metal centre is in a distorted octahedral CoCl(2)N(4) coordination with the Cl atoms in the axial positions. In the crys...

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Detalles Bibliográficos
Autores principales: Zhu, Hai-Bin, Li, Lei, Ji, Jun-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969327/
https://www.ncbi.nlm.nih.gov/pubmed/21582712
http://dx.doi.org/10.1107/S1600536809022636
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author Zhu, Hai-Bin
Li, Lei
Ji, Jun-Feng
author_facet Zhu, Hai-Bin
Li, Lei
Ji, Jun-Feng
author_sort Zhu, Hai-Bin
collection PubMed
description The asymmetric unit of the title compound, [CoCl(2)(C(18)H(12)N(6)S)], contains one half-mol­ecule situated on a twofold rotation axis which passes through the Co and S atoms. The metal centre is in a distorted octahedral CoCl(2)N(4) coordination with the Cl atoms in the axial positions. In the crystal structure, inter­molecular C—H⋯Cl inter­actions help to establish the packing.
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spelling pubmed-29693272010-12-30 {Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II) Zhu, Hai-Bin Li, Lei Ji, Jun-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [CoCl(2)(C(18)H(12)N(6)S)], contains one half-mol­ecule situated on a twofold rotation axis which passes through the Co and S atoms. The metal centre is in a distorted octahedral CoCl(2)N(4) coordination with the Cl atoms in the axial positions. In the crystal structure, inter­molecular C—H⋯Cl inter­actions help to establish the packing. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969327/ /pubmed/21582712 http://dx.doi.org/10.1107/S1600536809022636 Text en © Zhu et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Hai-Bin
Li, Lei
Ji, Jun-Feng
{Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II)
title {Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II)
title_full {Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II)
title_fullStr {Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II)
title_full_unstemmed {Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II)
title_short {Bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(II)
title_sort {bis[4-(2-pyrid­yl)pyrimidin-2-yl]sulfane}dichloridocobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969327/
https://www.ncbi.nlm.nih.gov/pubmed/21582712
http://dx.doi.org/10.1107/S1600536809022636
work_keys_str_mv AT zhuhaibin bis42pyridylpyrimidin2ylsulfanedichloridocobaltii
AT lilei bis42pyridylpyrimidin2ylsulfanedichloridocobaltii
AT jijunfeng bis42pyridylpyrimidin2ylsulfanedichloridocobaltii

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