Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate

In the title compound, [FeCl(2)(C(24)H(21)N(7))]Cl·C(4)H(8)O·H(2)O, the Fe(III) atom is coordinated by four N atoms of the polybenzimidazole ligand and two Cl atoms in a distorted octa­hedral environment. The cation, anion, the uncoordinated water mol­ecule and the THF solvent molecule are linked by...

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Detalles Bibliográficos
Autor principal: Wang, Dong’e
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969328/
https://www.ncbi.nlm.nih.gov/pubmed/21582746
http://dx.doi.org/10.1107/S1600536809023423
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author Wang, Dong’e
author_facet Wang, Dong’e
author_sort Wang, Dong’e
collection PubMed
description In the title compound, [FeCl(2)(C(24)H(21)N(7))]Cl·C(4)H(8)O·H(2)O, the Fe(III) atom is coordinated by four N atoms of the polybenzimidazole ligand and two Cl atoms in a distorted octa­hedral environment. The cation, anion, the uncoordinated water mol­ecule and the THF solvent molecule are linked by hydrogen bonds into a three-dimensional network structure. The THF molecule is disordered with two sets of sites in a 0.58 (1):0.42 (2) ratio..
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spelling pubmed-29693282010-12-30 Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate Wang, Dong’e Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [FeCl(2)(C(24)H(21)N(7))]Cl·C(4)H(8)O·H(2)O, the Fe(III) atom is coordinated by four N atoms of the polybenzimidazole ligand and two Cl atoms in a distorted octa­hedral environment. The cation, anion, the uncoordinated water mol­ecule and the THF solvent molecule are linked by hydrogen bonds into a three-dimensional network structure. The THF molecule is disordered with two sets of sites in a 0.58 (1):0.42 (2) ratio.. International Union of Crystallography 2009-06-27 /pmc/articles/PMC2969328/ /pubmed/21582746 http://dx.doi.org/10.1107/S1600536809023423 Text en © Dong'e Wang 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Dong’e
Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate
title Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate
title_full Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate
title_fullStr Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate
title_full_unstemmed Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate
title_short Dichlorido[tris­(1H-benzimidazol-2-ylmeth­yl)amine-κ(4) N,N (3),N (3′),N (3′′)]iron(III) chloride tetra­hydro­furan monosolvate monohydrate
title_sort dichlorido[tris­(1h-benzimidazol-2-ylmeth­yl)amine-κ(4) n,n (3),n (3′),n (3′′)]iron(iii) chloride tetra­hydro­furan monosolvate monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969328/
https://www.ncbi.nlm.nih.gov/pubmed/21582746
http://dx.doi.org/10.1107/S1600536809023423
work_keys_str_mv AT wangdonge dichloridotris1hbenzimidazol2ylmethylaminek4nn3n3n3ironiiichloridetetrahydrofuranmonosolvatemonohydrate

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