Bis(2,4,6-trimethyl­phen­yl)zinc(II)

The title compound, [Zn(C(9)H(11))(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethyl­phen­yl), crystallizes with a quarter of a mol­ecule in the asymmetric unit. The Zn(II) atom is in a strictly linear environment with a Zn—C bond length of 1.951 (5) Å. Due to the imposed 2/m symmetry, both aromatic...

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Detalles Bibliográficos
Autores principales: Krieck, Sven, Görls, Helmar, Westerhausen, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969329/
https://www.ncbi.nlm.nih.gov/pubmed/21582733
http://dx.doi.org/10.1107/S1600536809023186
Descripción
Sumario:The title compound, [Zn(C(9)H(11))(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethyl­phen­yl), crystallizes with a quarter of a mol­ecule in the asymmetric unit. The Zn(II) atom is in a strictly linear environment with a Zn—C bond length of 1.951 (5) Å. Due to the imposed 2/m symmetry, both aromatic rings are coplanar. One of the methyl groups is disordered over two equally occupied positions.

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