Bis(2,4,6-trimethyl­phen­yl)zinc(II)

The title compound, [Zn(C(9)H(11))(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethyl­phen­yl), crystallizes with a quarter of a mol­ecule in the asymmetric unit. The Zn(II) atom is in a strictly linear environment with a Zn—C bond length of 1.951 (5) Å. Due to the imposed 2/m symmetry, both aromatic...

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Detalles Bibliográficos
Autores principales: Krieck, Sven, Görls, Helmar, Westerhausen, Matthias
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969329/
https://www.ncbi.nlm.nih.gov/pubmed/21582733
http://dx.doi.org/10.1107/S1600536809023186
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author Krieck, Sven
Görls, Helmar
Westerhausen, Matthias
author_facet Krieck, Sven
Görls, Helmar
Westerhausen, Matthias
author_sort Krieck, Sven
collection PubMed
description The title compound, [Zn(C(9)H(11))(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethyl­phen­yl), crystallizes with a quarter of a mol­ecule in the asymmetric unit. The Zn(II) atom is in a strictly linear environment with a Zn—C bond length of 1.951 (5) Å. Due to the imposed 2/m symmetry, both aromatic rings are coplanar. One of the methyl groups is disordered over two equally occupied positions.
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spelling pubmed-29693292010-12-30 Bis(2,4,6-trimethyl­phen­yl)zinc(II) Krieck, Sven Görls, Helmar Westerhausen, Matthias Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zn(C(9)H(11))(2)] or Mes(2)Zn (Mes = mesityl = 2,4,6-trimethyl­phen­yl), crystallizes with a quarter of a mol­ecule in the asymmetric unit. The Zn(II) atom is in a strictly linear environment with a Zn—C bond length of 1.951 (5) Å. Due to the imposed 2/m symmetry, both aromatic rings are coplanar. One of the methyl groups is disordered over two equally occupied positions. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969329/ /pubmed/21582733 http://dx.doi.org/10.1107/S1600536809023186 Text en © Krieck et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Krieck, Sven
Görls, Helmar
Westerhausen, Matthias
Bis(2,4,6-trimethyl­phen­yl)zinc(II)
title Bis(2,4,6-trimethyl­phen­yl)zinc(II)
title_full Bis(2,4,6-trimethyl­phen­yl)zinc(II)
title_fullStr Bis(2,4,6-trimethyl­phen­yl)zinc(II)
title_full_unstemmed Bis(2,4,6-trimethyl­phen­yl)zinc(II)
title_short Bis(2,4,6-trimethyl­phen­yl)zinc(II)
title_sort bis(2,4,6-trimethyl­phen­yl)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969329/
https://www.ncbi.nlm.nih.gov/pubmed/21582733
http://dx.doi.org/10.1107/S1600536809023186
work_keys_str_mv AT kriecksven bis246trimethylphenylzincii
AT gorlshelmar bis246trimethylphenylzincii
AT westerhausenmatthias bis246trimethylphenylzincii

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