2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole

The mol­ecule of the title compound, C(18)H(28)N(2), composed of two 2,5-dimethyl­pyrrole groups linked by a hexane chain, lies across a crystallographic inversion centre. The mean plane of the pyrrole ring is almost perpendicular to the mean plane of the central chain, making a dihedral angle of 89...

Descripción completa

Detalles Bibliográficos
Autores principales: Santos, Ana C., Ramos Silva, Manuela, Monsanto, Paula V., Matos Beja, Ana, Sobral, Abilio J. F. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969330/
https://www.ncbi.nlm.nih.gov/pubmed/21582868
http://dx.doi.org/10.1107/S1600536809021965
_version_ 1782190115613835264
author Santos, Ana C.
Ramos Silva, Manuela
Monsanto, Paula V.
Matos Beja, Ana
Sobral, Abilio J. F. N.
author_facet Santos, Ana C.
Ramos Silva, Manuela
Monsanto, Paula V.
Matos Beja, Ana
Sobral, Abilio J. F. N.
author_sort Santos, Ana C.
collection PubMed
description The mol­ecule of the title compound, C(18)H(28)N(2), composed of two 2,5-dimethyl­pyrrole groups linked by a hexane chain, lies across a crystallographic inversion centre. The mean plane of the pyrrole ring is almost perpendicular to the mean plane of the central chain, making a dihedral angle of 89.09 (8)°. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions.
format Text
id pubmed-2969330
institution National Center for Biotechnology Information
language English
publishDate 2009
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29693302010-12-30 2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole Santos, Ana C. Ramos Silva, Manuela Monsanto, Paula V. Matos Beja, Ana Sobral, Abilio J. F. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers The mol­ecule of the title compound, C(18)H(28)N(2), composed of two 2,5-dimethyl­pyrrole groups linked by a hexane chain, lies across a crystallographic inversion centre. The mean plane of the pyrrole ring is almost perpendicular to the mean plane of the central chain, making a dihedral angle of 89.09 (8)°. The crystal structure is stabilized by inter­molecular C—H⋯π inter­actions. International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969330/ /pubmed/21582868 http://dx.doi.org/10.1107/S1600536809021965 Text en © Santos et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Santos, Ana C.
Ramos Silva, Manuela
Monsanto, Paula V.
Matos Beja, Ana
Sobral, Abilio J. F. N.
2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole
title 2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole
title_full 2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole
title_fullStr 2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole
title_full_unstemmed 2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole
title_short 2,2′,5,5′-Tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1H-pyrrole
title_sort 2,2′,5,5′-tetra­methyl-1,1′-(hexane-1,6-di­yl)di-1h-pyrrole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969330/
https://www.ncbi.nlm.nih.gov/pubmed/21582868
http://dx.doi.org/10.1107/S1600536809021965
work_keys_str_mv AT santosanac 2255tetramethyl11hexane16diyldi1hpyrrole
AT ramossilvamanuela 2255tetramethyl11hexane16diyldi1hpyrrole
AT monsantopaulav 2255tetramethyl11hexane16diyldi1hpyrrole
AT matosbejaana 2255tetramethyl11hexane16diyldi1hpyrrole
AT sobralabiliojfn 2255tetramethyl11hexane16diyldi1hpyrrole

Ejemplares similares