3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione

The title compound, C(14)H(11)NO(2)S(2), was synthesized by reaction of 2-(1,3-dithio­lan-2-yl­idene)-3-oxo-N-phenyl­butanamide with N,N′-dimethyl­formamide dimethyl acetal in N,N′-dimethyl­formamide. The mol­ecule exhibits a V-shaped conformation in the crystal, with a dihedral angle of 65.9 (2)° b...

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Detalles Bibliográficos
Autores principales: Li, Lei-Jiao, Li, Yan, Hao, Xi-Yun, Sun, Xiu-Yun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969332/
https://www.ncbi.nlm.nih.gov/pubmed/21582876
http://dx.doi.org/10.1107/S1600536809021862
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author Li, Lei-Jiao
Li, Yan
Hao, Xi-Yun
Sun, Xiu-Yun
author_facet Li, Lei-Jiao
Li, Yan
Hao, Xi-Yun
Sun, Xiu-Yun
author_sort Li, Lei-Jiao
collection PubMed
description The title compound, C(14)H(11)NO(2)S(2), was synthesized by reaction of 2-(1,3-dithio­lan-2-yl­idene)-3-oxo-N-phenyl­butanamide with N,N′-dimethyl­formamide dimethyl acetal in N,N′-dimethyl­formamide. The mol­ecule exhibits a V-shaped conformation in the crystal, with a dihedral angle of 65.9 (2)° between the benzene and pyridine rings. In the crystal. C—H⋯O and C—H⋯S interactions are observed. Two C atoms of the dithiolane ring are disordered with occupancies in the ratio 0.541 (13)/0.459 (13).
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spelling pubmed-29693322010-12-30 3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione Li, Lei-Jiao Li, Yan Hao, Xi-Yun Sun, Xiu-Yun Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(11)NO(2)S(2), was synthesized by reaction of 2-(1,3-dithio­lan-2-yl­idene)-3-oxo-N-phenyl­butanamide with N,N′-dimethyl­formamide dimethyl acetal in N,N′-dimethyl­formamide. The mol­ecule exhibits a V-shaped conformation in the crystal, with a dihedral angle of 65.9 (2)° between the benzene and pyridine rings. In the crystal. C—H⋯O and C—H⋯S interactions are observed. Two C atoms of the dithiolane ring are disordered with occupancies in the ratio 0.541 (13)/0.459 (13). International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969332/ /pubmed/21582876 http://dx.doi.org/10.1107/S1600536809021862 Text en © Li et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Lei-Jiao
Li, Yan
Hao, Xi-Yun
Sun, Xiu-Yun
3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione
title 3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione
title_full 3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione
title_fullStr 3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione
title_full_unstemmed 3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione
title_short 3-(1,3-Dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1H,3H)-dione
title_sort 3-(1,3-dithio­lan-2-yl­idene)-1-phenyl­pyridine-2,4(1h,3h)-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969332/
https://www.ncbi.nlm.nih.gov/pubmed/21582876
http://dx.doi.org/10.1107/S1600536809021862
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