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Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate

In the title compound, [Cu(C(2)H(8)N(2))(2)](C(12)H(6)N(2)O(4)S(2))·1.5H(2)O, there are two half-molecules of the cationic complex in the asymmetric unit. The Cu(2+) ions lie on inversion centres and are octa­hedrally coordinated by two ethyl­enediamine (en) and two aqua ligands in a typical Jahn–Te...

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Detalles Bibliográficos
Autores principales: Yazicilar, Turan Kaya, Demir, Serkan, Uçar, Ibrahim, Kazak, Canan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969337/
https://www.ncbi.nlm.nih.gov/pubmed/21582723
http://dx.doi.org/10.1107/S1600536809022612
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author Yazicilar, Turan Kaya
Demir, Serkan
Uçar, Ibrahim
Kazak, Canan
author_facet Yazicilar, Turan Kaya
Demir, Serkan
Uçar, Ibrahim
Kazak, Canan
author_sort Yazicilar, Turan Kaya
collection PubMed
description In the title compound, [Cu(C(2)H(8)N(2))(2)](C(12)H(6)N(2)O(4)S(2))·1.5H(2)O, there are two half-molecules of the cationic complex in the asymmetric unit. The Cu(2+) ions lie on inversion centres and are octa­hedrally coordinated by two ethyl­enediamine (en) and two aqua ligands in a typical Jahn–Teller distorted environment with the water O atoms in the axial positions. Two 2-mercaptonicotinate units (mnic) are linked by a disulfide bridge. All the ethyl­enediamine N—H and O—H groups form inter­molecular hydrogen bonds with acceptor O and N atoms, giving rise to a three-dimensional network. One of the uncoordinated water molecules has a site occupation factor of 0.5.
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spelling pubmed-29693372010-12-30 Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate Yazicilar, Turan Kaya Demir, Serkan Uçar, Ibrahim Kazak, Canan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(8)N(2))(2)](C(12)H(6)N(2)O(4)S(2))·1.5H(2)O, there are two half-molecules of the cationic complex in the asymmetric unit. The Cu(2+) ions lie on inversion centres and are octa­hedrally coordinated by two ethyl­enediamine (en) and two aqua ligands in a typical Jahn–Teller distorted environment with the water O atoms in the axial positions. Two 2-mercaptonicotinate units (mnic) are linked by a disulfide bridge. All the ethyl­enediamine N—H and O—H groups form inter­molecular hydrogen bonds with acceptor O and N atoms, giving rise to a three-dimensional network. One of the uncoordinated water molecules has a site occupation factor of 0.5. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969337/ /pubmed/21582723 http://dx.doi.org/10.1107/S1600536809022612 Text en © Yazicilar et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yazicilar, Turan Kaya
Demir, Serkan
Uçar, Ibrahim
Kazak, Canan
Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate
title Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate
title_full Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate
title_fullStr Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate
title_full_unstemmed Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate
title_short Diaqua­bis(ethyl­enediamine-κ(2) N,N′)copper(II) 2,2′-dithio­dinicotinate sesquihydrate
title_sort diaqua­bis(ethyl­enediamine-κ(2) n,n′)copper(ii) 2,2′-dithio­dinicotinate sesquihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969337/
https://www.ncbi.nlm.nih.gov/pubmed/21582723
http://dx.doi.org/10.1107/S1600536809022612
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