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Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate
In the title compound, [Cu(C(2)H(8)N(2))(2)](C(12)H(6)N(2)O(4)S(2))·1.5H(2)O, there are two half-molecules of the cationic complex in the asymmetric unit. The Cu(2+) ions lie on inversion centres and are octahedrally coordinated by two ethylenediamine (en) and two aqua ligands in a typical Jahn–Te...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2009
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969337/ https://www.ncbi.nlm.nih.gov/pubmed/21582723 http://dx.doi.org/10.1107/S1600536809022612 |
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author | Yazicilar, Turan Kaya Demir, Serkan Uçar, Ibrahim Kazak, Canan |
author_facet | Yazicilar, Turan Kaya Demir, Serkan Uçar, Ibrahim Kazak, Canan |
author_sort | Yazicilar, Turan Kaya |
collection | PubMed |
description | In the title compound, [Cu(C(2)H(8)N(2))(2)](C(12)H(6)N(2)O(4)S(2))·1.5H(2)O, there are two half-molecules of the cationic complex in the asymmetric unit. The Cu(2+) ions lie on inversion centres and are octahedrally coordinated by two ethylenediamine (en) and two aqua ligands in a typical Jahn–Teller distorted environment with the water O atoms in the axial positions. Two 2-mercaptonicotinate units (mnic) are linked by a disulfide bridge. All the ethylenediamine N—H and O—H groups form intermolecular hydrogen bonds with acceptor O and N atoms, giving rise to a three-dimensional network. One of the uncoordinated water molecules has a site occupation factor of 0.5. |
format | Text |
id | pubmed-2969337 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2009 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29693372010-12-30 Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate Yazicilar, Turan Kaya Demir, Serkan Uçar, Ibrahim Kazak, Canan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(2)H(8)N(2))(2)](C(12)H(6)N(2)O(4)S(2))·1.5H(2)O, there are two half-molecules of the cationic complex in the asymmetric unit. The Cu(2+) ions lie on inversion centres and are octahedrally coordinated by two ethylenediamine (en) and two aqua ligands in a typical Jahn–Teller distorted environment with the water O atoms in the axial positions. Two 2-mercaptonicotinate units (mnic) are linked by a disulfide bridge. All the ethylenediamine N—H and O—H groups form intermolecular hydrogen bonds with acceptor O and N atoms, giving rise to a three-dimensional network. One of the uncoordinated water molecules has a site occupation factor of 0.5. International Union of Crystallography 2009-06-20 /pmc/articles/PMC2969337/ /pubmed/21582723 http://dx.doi.org/10.1107/S1600536809022612 Text en © Yazicilar et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yazicilar, Turan Kaya Demir, Serkan Uçar, Ibrahim Kazak, Canan Diaquabis(ethylenediamine-κ(2) N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate |
title | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate |
title_full | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate |
title_fullStr | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate |
title_full_unstemmed | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate |
title_short | Diaquabis(ethylenediamine-κ(2)
N,N′)copper(II) 2,2′-dithiodinicotinate sesquihydrate |
title_sort | diaquabis(ethylenediamine-κ(2)
n,n′)copper(ii) 2,2′-dithiodinicotinate sesquihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969337/ https://www.ncbi.nlm.nih.gov/pubmed/21582723 http://dx.doi.org/10.1107/S1600536809022612 |
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