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Diaqua­bis(2-bromo­benzoato-κO)bis­(nicotinamide-κN (1))nickel(II)

The title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two 2-bromo­benzoate (BB) ligands, two nicotinamide (NA) ligands and two water mol­ecules, all of them being monodentate. The four O atoms in the equatorial plane around the Ni atom form a...

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Detalles Bibliográficos
Autores principales: Hökelek, Tuncer, Yılmaz, Filiz, Tercan, Barış, Özbek, F. Elif, Necefoğlu, Hacali
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969345/
https://www.ncbi.nlm.nih.gov/pubmed/21582699
http://dx.doi.org/10.1107/S1600536809021710
Descripción
Sumario:The title Ni(II) complex, [Ni(C(7)H(4)BrO(2))(2)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], is centrosymmetric. It contains two 2-bromo­benzoate (BB) ligands, two nicotinamide (NA) ligands and two water mol­ecules, all of them being monodentate. The four O atoms in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octa­hedral coordination is completed by the two N atoms of the NA ligands in the axial positions. The dihedral angle between the carboxyl­ate group and the adjacent benzene ring is 30.81 (17)°, while the pyridine and benzene rings are oriented at a dihedral angle of 84.66 (6)°. In the crystal structure, O—H⋯O and N—H⋯O hydrogen bonds link the mol­ecules into a supra­molecular structure. A weak C—H⋯π inter­action is also found.