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(Acetone-2κO){μ-6,6′-dimeth­oxy-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato-κ(8)1:2O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)terbium(III)

In the title heteronuclear complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimeth­oxy-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand (L) and an O atom from the acetone mol­ecule in a square-pyr...

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Detalles Bibliográficos
Autores principales: Sun, Wen-Bin, Yan, Peng-Fei, Li, Guang-Ming, Hou, Guang-Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969354/
https://www.ncbi.nlm.nih.gov/pubmed/21582709
http://dx.doi.org/10.1107/S1600536809022077
Descripción
Sumario:In the title heteronuclear complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimeth­oxy-2,2′-[propane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolate ligand (L) and an O atom from the acetone mol­ecule in a square-pyramidal geometry. The Tb(III) ion is ten-coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the L ligand. In L, the CH(2)–CH–CH(3) fragment is disordered over two conformations, with refined occupancies of 0.725 (11) and 0.275 (11).