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(Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)terbium(III)
In the title heteronuclear complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand (L) and an O atom from the acetone molecule in a square-pyr...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2009
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969354/ https://www.ncbi.nlm.nih.gov/pubmed/21582709 http://dx.doi.org/10.1107/S1600536809022077 |
| _version_ | 1782190123461378048 |
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| author | Sun, Wen-Bin Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng |
| author_facet | Sun, Wen-Bin Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng |
| author_sort | Sun, Wen-Bin |
| collection | PubMed |
| description | In the title heteronuclear complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand (L) and an O atom from the acetone molecule in a square-pyramidal geometry. The Tb(III) ion is ten-coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the L ligand. In L, the CH(2)–CH–CH(3) fragment is disordered over two conformations, with refined occupancies of 0.725 (11) and 0.275 (11). |
| format | Text |
| id | pubmed-2969354 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2009 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29693542010-12-30 (Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)terbium(III) Sun, Wen-Bin Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title heteronuclear complex, [CuTb(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolate ligand (L) and an O atom from the acetone molecule in a square-pyramidal geometry. The Tb(III) ion is ten-coordinated by six O atoms from three chelating nitrate ligands and four O atoms from the L ligand. In L, the CH(2)–CH–CH(3) fragment is disordered over two conformations, with refined occupancies of 0.725 (11) and 0.275 (11). International Union of Crystallography 2009-06-17 /pmc/articles/PMC2969354/ /pubmed/21582709 http://dx.doi.org/10.1107/S1600536809022077 Text en © Sun et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sun, Wen-Bin Yan, Peng-Fei Li, Guang-Ming Hou, Guang-Feng (Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O (6),O (1),O (1′),O (6′):O (1),N,N′,O (1′)}tris(nitrato-1κ(2) O,O′)copper(II)terbium(III) |
| title | (Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)terbium(III) |
| title_full | (Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)terbium(III) |
| title_fullStr | (Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)terbium(III) |
| title_full_unstemmed | (Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)terbium(III) |
| title_short | (Acetone-2κO){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2O
(6),O
(1),O
(1′),O
(6′):O
(1),N,N′,O
(1′)}tris(nitrato-1κ(2)
O,O′)copper(II)terbium(III) |
| title_sort | (acetone-2κo){μ-6,6′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato-κ(8)1:2o
(6),o
(1),o
(1′),o
(6′):o
(1),n,n′,o
(1′)}tris(nitrato-1κ(2)
o,o′)copper(ii)terbium(iii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969354/ https://www.ncbi.nlm.nih.gov/pubmed/21582709 http://dx.doi.org/10.1107/S1600536809022077 |
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