5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione

The title compound, C(15)H(18)N(4)O(3), was formed by the reaction of methanol with 5-ethyl-1,3-dimethyl­alloxazinium perchlorate. Its structure mimics those of possible flavin inter­mediates in flavoenzymes. The heterocyclic rings are substituted with methyl, ethyl and meth­oxy groups. The central...

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Detalles Bibliográficos
Autores principales: Ménová, Petra, Eigner, Václav, Cibulka, Radek, Čejka, Jan, Dvořáková, Hana
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969355/
https://www.ncbi.nlm.nih.gov/pubmed/21582825
http://dx.doi.org/10.1107/S1600536809020856
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author Ménová, Petra
Eigner, Václav
Cibulka, Radek
Čejka, Jan
Dvořáková, Hana
author_facet Ménová, Petra
Eigner, Václav
Cibulka, Radek
Čejka, Jan
Dvořáková, Hana
author_sort Ménová, Petra
collection PubMed
description The title compound, C(15)H(18)N(4)O(3), was formed by the reaction of methanol with 5-ethyl-1,3-dimethyl­alloxazinium perchlorate. Its structure mimics those of possible flavin inter­mediates in flavoenzymes. The heterocyclic rings are substituted with methyl, ethyl and meth­oxy groups. The central tricyclic skeleton is bent due to the presence of an sp (3) C atom. There are weak inter­molecular C—H⋯O inter­actions in the structure, forming a three-dimensional network.
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spelling pubmed-29693552010-12-30 5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione Ménová, Petra Eigner, Václav Cibulka, Radek Čejka, Jan Dvořáková, Hana Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(18)N(4)O(3), was formed by the reaction of methanol with 5-ethyl-1,3-dimethyl­alloxazinium perchlorate. Its structure mimics those of possible flavin inter­mediates in flavoenzymes. The heterocyclic rings are substituted with methyl, ethyl and meth­oxy groups. The central tricyclic skeleton is bent due to the presence of an sp (3) C atom. There are weak inter­molecular C—H⋯O inter­actions in the structure, forming a three-dimensional network. International Union of Crystallography 2009-06-10 /pmc/articles/PMC2969355/ /pubmed/21582825 http://dx.doi.org/10.1107/S1600536809020856 Text en © Ménová et al. 2009 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ménová, Petra
Eigner, Václav
Cibulka, Radek
Čejka, Jan
Dvořáková, Hana
5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione
title 5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione
title_full 5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione
title_fullStr 5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione
title_full_unstemmed 5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione
title_short 5-Ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1H,3H)dione
title_sort 5-ethyl-4a-meth­oxy-1,3-dimethyl-4a,5-dihydro­benzo[g]pteridine-2,4(1h,3h)dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969355/
https://www.ncbi.nlm.nih.gov/pubmed/21582825
http://dx.doi.org/10.1107/S1600536809020856
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AT dvorakovahana 5ethyl4amethoxy13dimethyl4a5dihydrobenzogpteridine241h3hdione

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