2,2′-Dimethyl-2,2′-(m-phenyl­ene­dimethyl­ene)propane­dinitrile

The title compound, C(16)H(14)N(4), features an aromatic ring with two 2,2′-dicyano­propyl residues in positions 1 and 3, which are located above and below the ring plane. The two residues differ in their conformation with respect to the aromatic ring: whereas one of the C(meth­yl)—C—C(methyl­ene)—C...

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Detalles Bibliográficos
Autores principales: Zhao, Junmei, Böhmer, Volker, Bolte, Michael
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2009
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969357/
https://www.ncbi.nlm.nih.gov/pubmed/21582920
http://dx.doi.org/10.1107/S1600536809023344
Descripción
Sumario:The title compound, C(16)H(14)N(4), features an aromatic ring with two 2,2′-dicyano­propyl residues in positions 1 and 3, which are located above and below the ring plane. The two residues differ in their conformation with respect to the aromatic ring: whereas one of the C(meth­yl)—C—C(methyl­ene)—C(aromatic) torsion angles is gauche [68.93 (12)°], the other one is fully staggered [177.63 (9)°]. The crystal structure is stabilized by C—H⋯N hydrogen-bonding inter­actions.

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